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In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called Dioxomolybdenum(VI) complexes with 3-methoxy salicylidene-N-alkyl substituted thiosemicarbazones. Synthesis, characterization, enzyme inhibition and antioxidant activity, published in 2019-10-15, which mentions a compound: 17524-05-9, mainly applied to crystal structure oxomolybdenum propylsalicylidene thiosemicarbazone; molybdenum alkylsalicylidene thiosemicarbazone preparation tyrosinase collagenase inhibition antioxidant activity, Category: nitriles-buliding-blocks.

3-Methoxysalicylidene N-alkyl-thiosemicarbazones (L) (alkyl is Pr, Bu, pentyl or hexyl) were synthesized. The reaction of the ONS donor ligands with [MoO2(acac)2] in MeOH yielded the mixed ligand complexes bearing a solvent mol. as co-ligand, [MoO2(L)(MeOH)]. The ligands and complexes were characterized by using anal. and spectroscopic methods. As a representative sample, the dioxomolybdenum(VI) complex of the N4-butyl-substituted thiosemicarbazone was crystallog. examined to ensure the expected structures. X-ray data showed a distorted octahedral environment of Mo center. Tyrosinase, collagenase inhibition and antioxidant properties of the compounds were studied using spectroscopic methods. The ligand and complexes exhibited the different inhibitory activities depending on N-alkyl substituents. Similarly, also the antioxidant capacity of the compounds changed in relation to the substituents.

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Lin, Yemao; Guo, Xiaodong; Hu, Mingjun; Liu, Bin; Dong, Yucheng; Wang, Xin; Li, Neng; Wang, Hong-En published an article about the compound: Bis(acetylacetonato)dioxomolybdenum(VI)( cas:17524-05-9,SMILESS:O=[Mo+2]12(O=C([CH-]C(C)=O1)C)(O=C([CH-]C(C)=O2)C)=O ).Quality Control of Bis(acetylacetonato)dioxomolybdenum(VI). Aromatic heterocyclic compounds can be classified according to the number of heteroatoms or the size of the ring. The authors also want to convey more information about this compound (cas:17524-05-9) through the article.

Layered metal sulfides are promising anode materials for sodium-ion batteries (SIBs) and capacitors owing to their distinctive crystal structures and large interlayer spacings, which are suitable for Na+ insertion/extraction However, low electronic conductivity, sluggish ion transfer and large volume variation of metal sulfides during sodiation/desodiation processes have hindered their practical application. In this work, we report the construction of a walnut-like core-shell MoS2@SnS heterostructure composite as an anode for SIBs with high capacity, remarkable rate and superior cycling stability. Exptl. observations and first-principles d. functional theory (DFT) calculations reveal that the enhanced electrochem. performances can be mainly ascribed to the boosted charge transfer and ion diffusion capabilities at the heterostructure interface driven by a self-building internal elec. field. Our findings herein may pave the way for the development of novel heterostructure composite materials for beyond lithium-ion batteries and capacitors.

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Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 17524-05-9, is researched, SMILESS is O=[Mo+2]12(O=C([CH-]C(C)=O1)C)(O=C([CH-]C(C)=O2)C)=O, Molecular C10H14MoO6Journal, Polyhedron called DMSO coordinated dioxidomolybdenum(VI) complexes chelated with 3-methoxybenzhydrazone related ligands: Synthesis, structural studies and in vitro cytotoxicity, Author is Asha, T. M.; Kurup, M. R. P., the main research direction is molybdenum oxido methoxybenzhydrazone complex preparation cytotoxicity electrochem thermal stability; Hirshfeld surface molybdenum oxido methoxybenzhydrazone complex; crystal structure molybdenum oxido methoxybenzhydrazone complex.HPLC of Formula: 17524-05-9.

Three new DMSO coordinated dioxidomolybdenum(VI) complexes [MoO2L3OMe(DMSO)] (1), [MoO2L4OMe(DMSO)] (2) and [MoO2L5OMe(DMSO)] (3) (where, L3OMe = 2-oxy-3-methoxybenzaldehyde-3-methoxy-benzhydrazonato, L4OMe = 2-oxy-4-methoxybenzaldehyde-3-methoxybenzhydrazonato and L5OMe = 2-oxy-5-methoxybenzaldehyde-3-methoxybenzhydrazonato) (Scheme 1) were synthesized by reacting [MoO2(acac)2] with the corresponding aroylhydrazone in presence of the solvent, DMSO and fully characterized. The various characterization techniques included elemental anal., spectroscopic techniques (IR, electronic and 1H NMR), thermogravimetric anal. and cyclic voltammetry. The mol. and crystal structures of 1, 2 and 3 were determined by single crystal X-ray diffraction method. In all complexes, the molybdenum atom displays a distorted octahedral geometry. In addition, the discussion on coordination geometries and non-covalent interactions were also supported using Hirshfeld surface anal. The in vitro cytotoxicity of the aroylhydrazone ligands and their molybdenum complexes against lymphoma ascites cell line demonstrated that the complexes are more cytotoxic than their corresponding ligands.

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Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: Bis(acetylacetonato)dioxomolybdenum(VI), is researched, Molecular C10H14MoO6, CAS is 17524-05-9, about Dielectric properties and electromagnetic wave absorbing performance of single-source-precursor synthesized Mo4.8Si3C0.6/SiC/Cfree nanocomposites with an in situ formed Nowotny phase.Quality Control of Bis(acetylacetonato)dioxomolybdenum(VI).

For the first time, dielec. properties and electromagnetic wave (EMW) absorbing performance of single-source-precursor derived Mo4.8Si3C0.6/SiC/Cfree ceramic nanocomposites with a highly elec. conductive intermetallic Nowotny phase (NP, i.e., Mo4.8Si3C0.6) are reported. High-temperature phase evolution of the nanocomposites reveals that free carbon (Cfree) plays a crucial role in the in situ formation of the NP, indicating that the microstructure of the nanocomposites can be tailored via mol. design of the single-source precursors. Compared with SiC/Cfree and MoSi2/SiC/Cfree nanocomposites obtained under the same conditions, the Mo4.8Si3C0.6/SiC/Cfree nanocomposites exhibit significantly enhanced EMW absorbing performance. A min. reflection loss (RL) of -59 dB was achieved at 8 GHz for the thickness of 2.46 mm, proving the superiority of the Mo4.8Si3C0.6/SiC/Cfree nanocomposite as an outstanding EMW absorbing material. On the basis of our previous discovery that the Mo4.8Si3C0.6 embedded in a SiC-based matrix with high sp. surface area exhibits excellent electrocatalytic properties suitable for the electrochem. hydrogen evolution reaction, the present results prove that Mo4.8Si3C0.6/SiC/Cfree nanocomposites have to be considered as novel multifunctional materials with tailorable microstructure and excellent performance in two different fields including electrochem. water splitting and EMW absorption.

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Reference of Bis(acetylacetonato)dioxomolybdenum(VI). The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: Bis(acetylacetonato)dioxomolybdenum(VI), is researched, Molecular C10H14MoO6, CAS is 17524-05-9, about Nowotny phase Mo3+2xSi3C0.6 dispersed in a porous SiC/C matrix: A novel catalyst for hydrogen evolution reaction. Author is Feng, Yao; Yu, Zhaoju; Schuch, Jona; Tao, Shasha; Wiehl, Leonore; Fasel, Claudia; Jaegermann, Wolfram; Riedel, Ralf.

The ternary Nowotny phase (NP), with a composition Mo3+2xSi3C0.6 (x = 0.9-0.764), is found to be catalytically active in the field of electrochem. water splitting. The NP embedded in a porous SiC/C nanocomposite matrix is synthesized via a single-source-precursor approach which involves the reaction of allylhydridopolycarbosilane with MoO2(acac)2. Thermal treatment of the single-source-precursor up to 1400°C in a protective atm. results in the in situ formation of nanocrystalline Mo3+2xSi3C0.6 immobilized in a thermally and corrosion-stable SiC/C matrix. The weight fractions of the observed crystalline phases Mo3+2xSi3C0.6 and SiC amount to ca. 28 (26) and 72 (74) wt%, resp., when prepared at 1400°C (1350°C). The porosity of the formed nanocomposite is adjusted by the addition of polystyrene (PS) as a pore former to the single-source-precursor resulting in a sp. surface area up to 206 m2/g. The electrocatalytic activity of the Mo3+2xSi3C0.6/C/SiC nanocomposite with respect to the hydrogen evolution reaction (HER) is characterized by low over potentials of 22 and 138 mV vs reversible hydrogen electrode (RHE) for applying 1 and 10 mA cm-2 of c.d., resp. The analyzed electrocatalytic performance exceeds that of most Mo-based electrocatalysts and shows high stability (over 90%) during 35 h.

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Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 17524-05-9, is researched, Molecular C10H14MoO6, about Engineering stable and fast sodium diffusion route by constructing hierarchical MoS2 hollow spheres, the main research direction is molybdenum sulfide hollow sphere sodium diffusion; Anode material; MoS(2) hollow spheres; Self-templating method; Sodium-ion battery.Synthetic Route of C10H14MoO6.

Two-dimensional layered transition metal dichalcogenides, such as MoS2, have been considered to be a promising anode material for sodium storage. However, their performance have been limited by the sluggish sodium diffusion kinetics. In this work, high performance anode material was obtained through constructing hierarchical MoS2 nanosheets assembled hollow spheres. The used self-templating method show more feasibility than the commonly reported template removal-involved routes. The prepared hollow structure can also provide rapid and stable electron/sodium ion transport without the assistance of conducting substrates, which enables the MoS2 anodes exhibit a high specific capacity of 527 mAh g-1 at 0.1 A g-1. Even at a high c.d. of 1 A g-1, capacity of 357 mAh g-1 can still be obtained after 500 cycles (capacity retention ≈94.5%). This work provides a facile way towards high performance MoS2 anode materials for sodium-ion battery.

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Name: Bis(acetylacetonato)dioxomolybdenum(VI). The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: Bis(acetylacetonato)dioxomolybdenum(VI), is researched, Molecular C10H14MoO6, CAS is 17524-05-9, about Styrene selective oxidation to benzaldehyde catalyzed by acylhydrazone Mo complexes: Reaction parameter effects and kinetics. Author is Yang, Shuang; Li, Gong; Yang, Yujie; Zhu, Mengdi; Fu, Yuejiao; Xing, Na; Shi, Lei.

Three acylhydrazone molybdenum complexes were synthesized for the first time: [MoO2L1(EtOH)] (1), [MoO2L2(EtOH)] (2), [MoO2L3(EtOH)] (3), [H2L1 = 4-bromo- N’-(3,5-dichloro-2-hydroxybenzylidene)benzohydrazide, H2L2 = N’-(3,5-dichloro-2-hydr- oxybenzylidene)-3-hydroxy-4-methoxybenzohydrazide, H2L3 = N’-(3,5-dichloro-2-hydro- xybenzylidene)-4-trifluoromethylbenzohydrazide]. They were characterized by FTIR, UV-visible, 1H NMR and thermogravimetric method. Their crystal structures were determined by single crystal x-ray diffraction. The Mo atoms in the complexes were in octahedral coordination, with the equatorial plane defined by the phenolate O, imino N and enalate O atoms of the hydrazone ligands and one oxo group, with the axial positions occupied by one oxo group and one ethanol O atom. The catalytic properties of the three complexes for styrene oxidation were studied.

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Application In Synthesis of Bis(acetylacetonato)dioxomolybdenum(VI). The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: Bis(acetylacetonato)dioxomolybdenum(VI), is researched, Molecular C10H14MoO6, CAS is 17524-05-9, about Hierarchically Porous MoS2-Carbon Hollow Rhomboids for Superior Performance of the Anode of Sodium-Ion Batteries. Author is Han, Lifeng; Wu, Shide; Hu, Zhe; Chen, Mingzhe; Ding, Junwei; Wang, Shiwen; Zhang, Yong; Guo, Dongjie; Zhang, Li; Cao, Shaokui; Chou, Shulei.

It is always challenging to fabricate two-dimensional transition-metal dichalcogenides into multiple hollow micro-/nanostructures with improved properties for various potential applications. Here, hierarchically porous MoS2-C hollow rhomboids (MCHRs) have been creatively synthesized via a facile self-templated solvothermal approach. It has been clarified that the obtained MCHRs assembled beneath ultrathin γ-MnS and carbon cohybridized MoS2 nanosheets under the structural direction of the MnMoO4·0.49H2O self-template. The prepared MCHR anode of sodium-ion batteries exhibited a reversible capacity of 506 mA h g-1 at 0.1 A g-1, ultrahigh rate capabilities up to 10 A g-1 with 310 mA h g-1, and exceptional stability over 3000 cycles. This study provides inspiration for the rational design of hierarchically porous hollow nanostructures with specific geometries as an excellent electrode material for outstanding performance energy storage equipment.

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Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: Bis(acetylacetonato)dioxomolybdenum(VI), is researched, Molecular C10H14MoO6, CAS is 17524-05-9, about Plasmon-Enhanced CO Selective Oxidation in H2 over Pt Nanoclusters Supported on Metallic Molybdenum Dioxide Nanocrystals.Electric Literature of C10H14MoO6.

The localized surface plasmonic resonance (LSPR) excitation in plasmonic nanoparticles is showing great promise in solar-driven chem. conversions, known as plasmon-induced catalysis. In exploring its enormous potential, constructing multicomponent structure with both LSPR absorption and catalytic active parts is an ideal way, while most studies are limited to metallic core-shell structure. Herein, hybrid nanostructure with plasmonic metal oxide (MoO2) and catalytic Pt nanoclusters is successfully designed. Under illumination, it not only demonstrates to be highly active for the preferential oxidation of CO in the presence of H2 (CO-PROX) but also shows a dramatically wide temperature range for the total conversion of CO. The pathway of plasmon-energy decay in MoO2 is clarified to selectively dissipate through catalytically active Pt sites in the form of hot carriers, thereby inducing efficient chem. transformation. These results may open an avenue in exploring plasmonic metal oxide materials to drive and modulate plasmon-induced catalysis under illumination.

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So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Li, Meixuan; Wang, Huiyuan; Zhu, Yun; Tian, Di; Wang, Ce; Lu, Xiaofeng researched the compound: Bis(acetylacetonato)dioxomolybdenum(VI)( cas:17524-05-9 ).Computed Properties of C10H14MoO6.They published the article 《Mo/Mo2C encapsulated in nitrogen-doped carbon nanofibers as efficiently integrated heterojunction electrocatalysts for hydrogen evolution reaction in wide pH range》 about this compound( cas:17524-05-9 ) in Applied Surface Science. Keywords: molybdenum carbide encapsulation nitrogen carbon nanofiber electrocatalyst; hydrogen evolution reaction electrocatalyst. We’ll tell you more about this compound (cas:17524-05-9).

It is extremely necessary to develop high-performance noble-metal-free hydrogen evolution reaction (HER) electrocatalysts applied over the whole pH values to replace expensive Pt-based catalysts. Herein, a typical metal-semiconductor heterostructure with metallic Mo and Mo2C nanoparticles encapsulated in nitrogen-doped carbon nanofibers (N-CNFs) is fabricated via the pyrolysis of electrospun polyacrylonitrile (PAN)/cellulose acetate (CA)/bis(acetylacetonato)dioxomolybdenum (MoO2(acac)2) nanofibers. The unique porous and channel-rich structure of Mo/Mo2C/N-CNFs can be manipulated by varying the mass ratio of polyacrylonitrile and cellulose acetate, leading to the exposure of abundant active centers and the acceleration of rapid mass transport. In addition, the synergetic effect among metal and semiconductor as well as the excellent conductivity of the N-CNFs result in excellent HER activity and stability over a wide pH range. To achieve the c.d. of 10 mA cm-2, the optimized Mo/Mo2C/N-CNFs exhibit overpotentials of 175, 162 and 294 mV in 0.5 M H2SO4, 1 M KOH and 0.1 M phosphate buffer solution (PBS), resp. This work provides a feasible approach to synthesize high-performance and economical hydrogen evolution electrocatalysts at all pH values for renewable energy-related applications.

In some applications, this compound(17524-05-9)Computed Properties of C10H14MoO6 is unique.If you want to know more details about this compound, you can contact with the author or consult more relevant literature.

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