Tag: M.W=300-400

Product Details of 17524-05-9. So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic. Compound: Bis(acetylacetonato)dioxomolybdenum(VI), is researched, Molecular C10H14MoO6, CAS is 17524-05-9, about Mo-catalysis-assisted expeditious synthesis of N-doped erythrocyte-like hollow porous carbons for sodium storage.

Rational design and construction, with appropriate approaches to achieve desired hollow interiors in carbonaceous materials, is a pivotal issue remaining to be resolved in realizing their widespread practical availability. Herein, we aim to provide a feasible and novel strategy to synthesize N-doped hollow porous carbons with pore sizes in the range of 0.5-1 nm through Mo-catalysis-assisted interfacial microemulsion polymerization combined with a carbonization process on a large scale. The morphol. of the as-prepared carbon materials can be controlled from solid spheres to erythrocyte-like hollow structures, and the particle sizes can be tuned from ∼50 nm to ∼10 μm. Such unusual hollow porous architectures might offer unique structure-dependent physiochem. properties and promising applications in many areas. As an example, we demonstrate that the erythrocyte-like carbon could exhibit remarkable electrochem. performance as an anode for sodium-ion batteries.

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Name: Bis(acetylacetonato)dioxomolybdenum(VI). The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: Bis(acetylacetonato)dioxomolybdenum(VI), is researched, Molecular C10H14MoO6, CAS is 17524-05-9, about Molybdenum(VI) complexes of hemilabile aroylhydrazone ligands as efficient catalysts for greener cyclooctene epoxidation: an experimental and theoretical approach. Author is Pisk, Jana; Rubcic, Mirta; Kuzman, Dino; Cindric, Marina; Agustin, Dominique; Vrdoljak, Visnja.

The focus of this work was on the synthesis, characterization and catalytic activity of Mo(VI) complexes with hemilabile polydentate ligands that show a high tendency to form discrete small-sized self-assembled structures. A series of mononuclear, [MoO2(L1 or 3)(MeOH)] (1a and 3a) and [MoO2(L1)(EtOH)] (1b), and dinuclear, [MoO2(L1-3)]2 (1-3), complexes was synthesized by using 2-aminobenzoylhydrazone ligands derived from salicylaldehyde (H2L1), 3-methoxy-2-hydroxybenzaldehyde (H2L2) and 4-methoxy-2-hydroxybenzaldehyde (H2L3). Different reaction conditions gave several crystalline forms of the dinuclear cyclic species [MoO2(L1 or 3)]2 (1-α, 1-β, 1-γ, 1·CH3CN, 3-α, 3-β and 3·2CH3CN), a feature which is observed for the first time in the case of the metallosupramol. compounds incorporating cis-MoO22+ subunits. These complexes were tested as catalysts for cyclooctene epoxidation under eco-friendly reaction conditions by using aqueous tert-Bu hydroperoxide as an oxidant without the addition of an organic solvent. The use of the hemilabile ligands provided the opportunity to employ relatively stable coordinatively saturated dinuclear Mo(VI) complexes, which in turn offered access to highly reactive pentacoordinated species in the presence of olefins. Lastly, the hemilabile ligand induced catalytic enhancement was addressed by using d. functional theory calculations

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So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Arfaoui, Jihene; Ghorbel, Abdelhamid; Petitto, Carolina; Delahay, Gerard researched the compound: Bis(acetylacetonato)dioxomolybdenum(VI)( cas:17524-05-9 ).Safety of Bis(acetylacetonato)dioxomolybdenum(VI).They published the article 《A new V2O5-MoO3-TiO2-SO42- nanostructured aerogel catalyst for diesel DeNOx technology》 about this compound( cas:17524-05-9 ) in New Journal of Chemistry. Keywords: vanadium oxide molybdenum titanium sulfur nanostructured; selective catalytic reduction aerogel catalyst diesel nitrogen oxygen technol. We’ll tell you more about this compound (cas:17524-05-9).

A new V2O5-MoO3-TiO2-SO42- nanostructured aerogel system, containing V and Mo loadings representative of the V2O5-MoO3/TiO2 com. SCR catalyst, was developed via a one step sol-gel method combined with the supercritical drying approach for the low temperature selective catalytic reduction of NO by NH3, in excess O2. The new V2O5-MoO3-TiO2-SO42- catalyst was analyzed via x-ray diffraction, N2-physisorption, H2-TPR, NH3-TPD, Raman spectroscopy, XPS and DR UV-vis spectroscopy. The elaboration and characterization of TiO2, V2O5-TiO2, MoO3-TiO2, V2O5-MoO3-TiO2, TiO2-SO42-, V2O5-TiO2-SO42- and MoO3-TiO2-SO42- aerogel samples were also reported in this work. The results prove the successful synthesis of nanostructured aerogel materials with good crystallinity of the TiO2 anatase phase, a developed mesoporous texture and a nanometer size as new SCR catalysts. V, Mo and SO42- were highly dispersed on the TiO2 surface, and their presence and the diverse interactions developed between them strongly affect the physicochem. properties and catalytic behavior of the derived sol-gel powders. Among all the samples investigated, the new V2O5-MoO3-TiO2-SO42- aerogel was the most efficient catalyst for the low temperature NO-SCR: compared to a V2O5-WO3/TiO2 com. catalyst (EUROCAT), it demonstrates similar SCR activity in the 200-375° temperature range, but, at higher temperatures (375-500°), it exhibits superior catalytic performance. A complete conversion of NO into N2 (100%) was achieved in the 450-500° temperature range over the new V2O5-MoO3-TiO2-SO42- nanostructured aerogel catalyst, when the NH3-SCR reaction was realized using 1000 ppm NO and 1000 ppm NH3, in the presence of 3.5% H2O.

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Related Products of 17524-05-9. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: Bis(acetylacetonato)dioxomolybdenum(VI), is researched, Molecular C10H14MoO6, CAS is 17524-05-9, about Immobilization of salen molybdenum complex on dendrimer functionalized magnetic nanoparticles and its catalytic activity for the epoxidation of olefins. Author is Niakan, Mahsa; Asadi, Zahra; Masteri-Farahani, Majid.

A novel catalyst was prepared by the immobilization of salen molybdenum complex on dendrimer functionalized magnetic nanoparticles. Fourier transform IR spectroscopy (FT-IR), thermogravimetric anal. (TGA), N2 adsorption-desorption isotherms, X-ray diffraction (XRD), SEM (SEM), transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy (EDX), XPS, vibrating sample magnetometry (VSM), inductively couple plasma at. emission spectroscopy (ICP-AES), and elemental anal. were used to characterize the catalyst. The synthesized catalyst was highly active and selective for the epoxidation of various olefins in the presence of tert-Bu hydroperoxide (TBHP) as oxidant. Notably, the catalyst could be separated easily by applying an external magnet and recycled up to six cycles without significant decrease in catalytic activity and selectivity.

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In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called Colloidally synthesized defect-rich MoSe2 nanosheets for superior catalytic activity, published in 2019-04-30, which mentions a compound: 17524-05-9, mainly applied to molybdenum diselenide nanosheet superior catalytic activity, Formula: C10H14MoO6.

Transition metal dichalcogenide (TMD) nanosheets (NSs) with defect-rich and vertically aligned edges are highly advantageous for various catalytic applications. However, colloidal synthesis of defect-rich NSs with thickness variation has been a challenging task. Here, we report a colloidal synthesis of 2H-MoSe2 NSs having a large number of defects and vertically aligned edges, where the thickness is varied by changing the amount of coordinating solvent. The Se-vacancies in these NSs have introduced defect sites which are corroborated by the presence of addnl. vibration modes in Raman spectra. These NSs exhibit electrocatalytic hydrogen evolution reaction performances with a low overpotential (210-225 mV) at 10mAcm-2 c.d. and a small Tafel slope (54-68 mV per decade). Moreover, these MoSe2 NSs are also employed as counter electrodes (CEs) for the fabrication of dye sensitized solar cells via a cost-effective and simplified procedure. The power conversion efficiencies of 7.02±0.18%, comparable with Pt CE (7.84±0.10%) could be routinely achieved. These results demonstrate a novel synthetic strategy to prepare layered TMDs with superior catalytic applications.

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So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Bao, Yujie; Chen, Ting; Zhu, Zhiliang; Zhang, Hua; Qiu, Yanling; Yin, Daqiang researched the compound: Bis(acetylacetonato)dioxomolybdenum(VI)( cas:17524-05-9 ).Name: Bis(acetylacetonato)dioxomolybdenum(VI).They published the article 《Mo2C/C catalyst as efficient peroxymonosulfate activator for carbamazepine degradation》 about this compound( cas:17524-05-9 ) in Chemosphere. Keywords: molybdenum carbide carbon catalyst peroxymonosulfate activator carbamazepine degradation; Advanced oxidation processes; Carbamazepine; Molybdenum carbide; Peroxymonosulfate activation; Water purification. We’ll tell you more about this compound (cas:17524-05-9).

Compared with generally reported Mo4+/Mo6+ redox cycle, the exposed Mo2+ active sites of Mo-based materials may have a superior potential to effectively activate PMS. However, Mo2+-involved materials as efficient catalysts in sulfate radical-based advanced oxidation processes (SR-AOPs) has rarely been researched. In this work, a spherical Mo2C-loaded carbon material, Mo2C/C, was prepared for the first time by hydrothermal-calcination method directly used as peroxymonosulfate (PMS) activator toward carbamazepine (CBZ) degradation The results showed that the Mo2C/C could effectively remove nearly 100% CBZ (5 mg.L-1) in the presence of 0.75 mM PMS within 75 min under the optimal conditions. It was attributed to the reductive Mo2+, as active sites, benefits to absorb PMS on the surface to trigger electron transmission, and the defective carbon structures accelerate the activation of PMS. Consequently, the efficient Mo2+/Mo4+/Mo6+ electron transfer was achieved, resulting in excellent catalysis. A series of reactive species including SO4.-, .OH and 1O2 species participated in CBZ oxidation degradation Derived from the superior stability and reusability of Mo2C/C, the removal rate of CBZ still maintained above 80% even after five consecutive cycles, which is expected to be applied in the wastewater treatment including pharmaceuticals in the future.

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The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: Bis(acetylacetonato)dioxomolybdenum(VI)(SMILESS: O=[Mo+2]12(O=C([CH-]C(C)=O1)C)(O=C([CH-]C(C)=O2)C)=O,cas:17524-05-9) is researched.Name: Bis(acetylacetonato)dioxomolybdenum(VI). The article 《Synthesis, spectral, structural and antibacterial studies of ONO donor aroylhydrazone and its Mo(VI) complex》 in relation to this compound, is published in Journal of Molecular Structure. Let’s take a look at the latest research on this compound (cas:17524-05-9).

A tridentate ONO donor aroylhydrazone, 3′,5′-dichloro-2′-hydroxyacetophenone-3-methoxybenzoylhydrazone monohydrate (H2CAB·H2O) and its cis-MoO2 complex [MoO2(CAB)(DMF)]2(DMF) (1) have been synthesized and characterized by elemental anal., LCMS, FT-IR, UV-Vis and 1H NMR. The mol. structures were confirmed by single crystal x-ray diffraction studies. H2CAB·H2O and 1 got crystallized in a triclinic space group P-1 as monohydrated and DMF solvated resp. The asym. unit of complex 1 contains two complex mols. All the synthesized compounds are subjected to in vitro antibacterial studies against a series of selected bacterial strains, by agar well diffusion method, using ampicillin as standard Both the compounds are more active against Escherichia coli.

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Electric Literature of C10H14MoO6. So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic. Compound: Bis(acetylacetonato)dioxomolybdenum(VI), is researched, Molecular C10H14MoO6, CAS is 17524-05-9, about Electrochemical Evolution of Pore-Confined Metallic Molybdenum in a Metal-Organic Framework (MOF) for All-MOF-Based Pseudocapacitors.

In this study, metallic molybdenum nanoparticles confined in the nanopores of a zirconium-based MOF (Zr-MOF), MOF-808, are prepared by a self-limiting decoration of spatially isolated Mo(VI) sites on the hexa-zirconium nodes of MOF-808, followed by the electrochem. reduction of Mo(VI) to metallic Mo. The obtained pore-confined Mo exhibits reversible redox activity in a neutral aqueous electrolyte and serves as the pseudocapacitive material for neg. electrodes. By introducing another MOF-based pseudocapacitive material that can be used for pos. electrodes, a manganese-decorated Zr-MOF-carbon nanotube nanocomposite, as a demonstration, all-Zr-MOF-based asym. pseudocapacitors with an aqueous electrolyte are fabricated.

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Synthetic Route of C10H14MoO6. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: Bis(acetylacetonato)dioxomolybdenum(VI), is researched, Molecular C10H14MoO6, CAS is 17524-05-9, about Effects of the catalytic system MoO2(acac)2-TBHP in polyisoprene epoxidation using experimental design. Author is Gregorio, Jose R.; Barbosa-Coutinho, Elisa; Gerbase, Annelise E.; Ferreira, Marcia Pires Fortes; Jacobi, Marly A. M..

The epoxidation of polydienes yields materials with improved properties, which can be tuned by the control of the epoxidation degree. In this work, we retake a known process, the epoxidation of polyisoprene, by a different approach, in which the quantification of parameters influencing the epoxidation, such as temperature, oxidant and catalyst concentration, and reaction time degree is evaluated. We measured the influence of each parameter, allowing anyone who aims a polymer with a certain degree of epoxidation to choose which conditions are best suitable for reaching his goal.

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Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: Bis(acetylacetonato)dioxomolybdenum(VI), is researched, Molecular C10H14MoO6, CAS is 17524-05-9, about Hierarchical nanoarchitectured hybrid electrodes based on ultrathin MoSe2 nanosheets on 3D ordered macroporous carbon frameworks for high-performance sodium-ion batteries.Electric Literature of C10H14MoO6.

Sodium-ion batteries (SIBs) have been considered a promising alternative to lithium-ion batteries for large-scale stationary energy storage due to their low cost and the abundant resources of sodium. Nevertheless, the lack of anodes with high capacity and long-term cycling stability seriously hinders the commercialization of SIBs. Herein, ultrathin 2D MoSe2 nanosheets (∼2 nm) strongly bonded on 3D ordered macroporous (3DOM) carbon are designed to greatly improve sodium storage. The resulting MoSe2@C composite delivers high capacity (410 mA h g-1 at 0.5 A g-1 after 100 cycles, considering the total weight of the active MoSe2@C), superior rate capability (279 mA h g-1 at 10 A g-1), and long-term cycling stability (384 mA h g-1 at 5 A g-1 after 2000 cycles). The enhanced electrochem. performance can be ascribed to synergistic effects between the hybrid structures constructed from 2D MoSe2 nanosheets and the 3DOM carbon architecture, which can provide expanded interlayer spacing (0.76 nm for a single layer) facilitating Na+ insertion/extraction, strong electronic coupling of Mo-C boosting the fast electron/ion transfer, and ordered 3D cavities accommodating the volume expansion and preventing the stacking of MoSe2 nanosheets upon cycling.

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