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In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called Application of molybdenum complexes for the oxidation of cyclohexane in acetonitrile, ionic liquid and supercritical CO2 media, a comparative study, published in 2020-02-29, which mentions a compound: 17524-05-9, mainly applied to cyclohexane oxidation molybdenum complex acetonitrile carbon dioxide ionic liquid, Computed Properties of C10H14MoO6.

The cis-dioxidomolybdenum(VI) complexes [MoO2(L1)] (1), [MoO2(L2)]·MeOH (2) and [MoO2(L3)] (3) were prepared by reaction of [MoO2(acac)2] with the corresponding aroyl hydrazone Schiff base H2L1 = 2,3-dihydroxy benzylidene-2-hydroxybenzohydrazide, H3L2 = 2,3-dihydroxy benzylidene-benzo hydrazide and H2L3 = (3,5-di-tert-butyl-2-hydroxy benzylidene)-2-hydroxybenzohydrazide, resp. The catalytic activities of these complexes towards cyclohexane (CyH) oxidation were examined and compared in CH3CN, ionic liquid (1-butyl-3-methylimidazolium hexafluorophosphate, [bmim][PF6]), supercritical carbon dioxide (SC-CO2), and SC-CO2/[bmim][PF6] mixed solvent. The yields in the ionic liquid (IL) are always higher than in CH3CN. A very high selectivity towards cyclohexanol is obtained in the SC-CO2 medium with all three complexes. The catalyst can be recycled with full preservation (3 cycles) of its activity in the SC-CO2 and SC-CO2/IL media.

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Most of the compounds have physiologically active properties, and their biological properties are often attributed to the heteroatoms contained in their molecules, and most of these heteroatoms also appear in cyclic structures. A Journal, International Journal of Hydrogen Energy called Ni-Mo nanoparticles stabilized by ether functionalized ionic polymer: A novel and efficient catalyst for hydrodeoxygenation of 4-methylanisole as a representative of lignin-derived pyrolysis bio-oils, Author is Saidi, Majid; Safaripour, Maryam, which mentions a compound: 17524-05-9, SMILESS is O=[Mo+2]12(O=C([CH-]C(C)=O1)C)(O=C([CH-]C(C)=O2)C)=O, Molecular C10H14MoO6, Safety of Bis(acetylacetonato)dioxomolybdenum(VI).

In the present study, nickel-molybdenum nanoparticles stabilized with ether functionalized ionic polymer were synthesized and utilized as a novel and efficient catalyst for hydrodeoxygenation of 4-methylanisole as a representative of lignin-derived bio-oil. The catalytic upgrading process was performed in the presence of hydrogen with a batch reactor at temperature of 80-200°C, hydrogen pressure of 10-50 bar, reaction time of 0.5-15 h and catalyst loading of 1-5 mol%. The major reaction classes during 4-methylanisole upgrading were hydrodeoxygenation and hydrogenolysis which resulted in production of 4-methylphenol, toluene, phenol and benzene as the main products. The exptl. results indicated that the catalytic activity of Ni-Mo (20%-80%) nanoparticles stabilized with ionic polymer is superior to that with low Mo content. Also, it is observed that the selectivity of deoxygenated products including toluene and benzene improves with increasing the Mo content of the catalyst. Finally, regarding to the excellent catalytic activity of synthesized nanocatalyst during upgrading process of bio-oil at mild operating condition, ether functionalized ionic polymer was introduced as an applicable and effective stabilizers for nickel-molybdenum nanoparticles.

The article 《Ni-Mo nanoparticles stabilized by ether functionalized ionic polymer: A novel and efficient catalyst for hydrodeoxygenation of 4-methylanisole as a representative of lignin-derived pyrolysis bio-oils》 also mentions many details about this compound(17524-05-9)Safety of Bis(acetylacetonato)dioxomolybdenum(VI), you can pay attention to it, because details determine success or failure

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Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 17524-05-9, is researched, Molecular C10H14MoO6, about Tuning Light-Driven Water Oxidation Efficiency of Molybdenum-Doped BiVO4 by Means of Multicomposite Catalysts Containing Nickel, Iron, and Chromium Oxides, the main research direction is molybdenum bismuth vanadate nickel iron chromium oxide water oxidation; bismuth vanadate; oxygen evolution; photoelectrocatalysis; transition metal oxides; water splitting.COA of Formula: C10H14MoO6.

Mo-doped BiVO4 has emerged as a promising material for photoelectrodes for photoelectrochem. water splitting, however, still shows a limited efficiency for light-driven water oxidation We present the influence of an oxygen-evolution catalyst composed of Ni, Fe, and Cr oxides on the activity of Mo:BiVO4 photoanodes. The photoanodes are prepared by spray-coating, enabling compositional and thickness gradients of the incorporated catalyst. Two different configurations are evaluated, namely with the catalyst embedded into the Mo:BiVO4 film or deposited on top of it. Both configurations provide a significantly different impact on the photoelectrocatalytic efficiency. Structural characterization of the materials by means of SEM, TEM and XRD as well as the photoelectrocatalytic activity investigated by means of an optical scanning droplet cell and in situ detection of oxygen using scanning photoelectrochem. microscopy are presented.

The article 《Tuning Light-Driven Water Oxidation Efficiency of Molybdenum-Doped BiVO4 by Means of Multicomposite Catalysts Containing Nickel, Iron, and Chromium Oxides》 also mentions many details about this compound(17524-05-9)COA of Formula: C10H14MoO6, you can pay attention to it, because details determine success or failure

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Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 17524-05-9, is researched, Molecular C10H14MoO6, about Synthesis and characterization of homobimetallic molybdenum(VI) complexes of a dihydrazone as efficient catalysts for the synthesis of hexahydroxyquinolines via multicomponent Hantzsch reaction, the main research direction is homobimetallic molybdenum complex catalyst aldehyde cyclohexanedione ethylacetoacetate Hantzsch; hexahydroxyquinolone preparation.Synthetic Route of C10H14MoO6.

Four homobimetallic molybdenum(VI) complexes [(MoO2)2L(D)2] (where D = methanol, dimethylsufoxide, imidazole and pyridine) derived from a multidentate hydrazone ligand, 1,4-bis(3-ethoxy-2-hydroxybenzaldehyde-carbohydrazonato)butane, H4L were synthesized by the reaction of the same with bis(acetylacetonato)dioxidomolybdenum(VI) in 1:2 ratio in presence of methanol, DMSO, imidazole and pyridine. The complexes are suggested to have six-coordinate octahedral stereochem. around molybdenum(VI) centers. The dihydrazone and the complexes synthesized are characterized by elemental anal., various spectroscopic techniques (like FT-IR, UV-Vis and 1H NMR) and TGA anal. The molybdenum complexes have been successfully utilized as catalysts for the synthesis of hexahydroxyquinolones via multicomponent Hantzsch reaction. Generally, decent conversions have been obtained.

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Reference:
Nitrile – Wikipedia,
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Most of the compounds have physiologically active properties, and their biological properties are often attributed to the heteroatoms contained in their molecules, and most of these heteroatoms also appear in cyclic structures. A Journal, Applied Organometallic Chemistry called Bis-dioxomolybdenum (VI) oxalyldihydrazone complexes: Synthesis, characterization, DFT studies, catalytic epoxidation potential, molecular modeling and biological evaluations, Author is Adam, Mohamed Shaker S.; Ahmed, Mohamed S. Mohamed; El-Hady, Omar M.; Shaaban, Saad, which mentions a compound: 17524-05-9, SMILESS is O=[Mo+2]12(O=C([CH-]C(C)=O1)C)(O=C([CH-]C(C)=O2)C)=O, Molecular C10H14MoO6, HPLC of Formula: 17524-05-9.

Two cis-bis-dioxomolybdenum oxalylsalicylidenedihydrazone complexes (MoO2L1 and MoO2L2) were synthesized via the complexation of dioxomolybdenum (VI) acetylacetonate with oxalylsalicylidenedihydrazone (H2L1) and p-sodium sulfonate oxalylsalicylidenedihydrazone (H2L2) bis-Schiff base chelating ligands, resp. The structures of the newly synthesized complexes were confirmed by 1H- and 13C-NMR, IR, UV-visible and mass spectra, as well as elemental analyses (EA) and conductivity measurements. The spectrophotometric continuous variation method revealed the formation of 2: 1 (metal: ligand molar ratios). DFT studies were applied for the ligands and their Mo-chelates. The bis-MoO2(VI) oxalyldihydrazone complexes showed remarkable catalytic sufficiency towards the selective (ep)oxidation of 1,2-cyclooctene, benzyl alc. and thiophene using H2O2 or tert-Bu hydroperoxide (tBuOOH) at 85°. Under aqueous conditions, the MoO2L2 (with p-sodium sulfonate substituent) exhibited superior that of the MoO2L1 (without p-NaSO3-group), highlighting the role of sodium sulfonate substituent in the catalytic progress of the Mo-chelate. The ligands (H2L1 and H2L2) and their corresponding Mo-complexes (MoO2L1 and MoO2L2) were assessed for their antitumor and antimicrobial activities. Also, the antioxidant activity was also evaluated using the 2,2-diphenyl-1-picrylhydrazyl (DPPH) and superoxide dismutase (SOD) assays. The binding nature between the Mo-complexes and calf thymus DNA (ctDNA) was also studied within spectroscopic and hydrodynamic techniques.

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In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called The Energy Level Regulation of CoMo Carbonate Hydroxide for the Enhanced Oxygen Evolution Reaction Activity, published in 2019-03-18, which mentions a compound: 17524-05-9, mainly applied to cobalt molybdenum carbonate hydroxide electrocatalyst oxygen evolution reaction, Category: nitriles-buliding-blocks.

The oxygen evolution reaction (OER) accompanied by multistep proton-coupled electron transfer is the decisive step of electrochem. water splitting due to the sluggish kinetics process. Enhancing the efficiency of water splitting indispensably requires stable and high-efficiency electrocatalysts for OER. The OER activity of electrocatalysts can be largely heightened by well adjusting their energy level and active sites. Herein, the amorphous iron cobalt molybdenum carbonate hydroxide core-shell microspheres (FeCoMo/CoMo) offer significant opportunities to improve the OER activity in both thermodn. and kinetics due to the appropriate matching of the energy level with the equilibrium potential of OER and the abundant active sites.The well-designed Fe0.25-CoMoCH/NF sample exhibits prominent activity toward OER with an overpotential as low as 232 mV to deliver a c.d. of 10 mA cm-2, a small Tafel slope of 46 mV dec-1, and excellent stability in alk. solution Mechanistic studies using a rotating ring-disk electrode confirm the four-electron pathway with high faradaic efficiency (97.7%) toward OER. This research provides a model system so as to tune the inherent catalytic activity of electrocatalysts.

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Wang, Cong; Xing, Na; Feng, Wenjing; Guo, Sihan; Liu, Mingyang; Xu, Yue; You, Zhonglu published the article 《New mononuclear dioxidomolybdenum(VI) complexes with hydrazone ligands: Synthesis, crystal structures and catalytic performance》. Keywords: preparation crystal structure mononuclear dioxidomolybdenum hydrazone complex; thermal decomposition mononuclear dioxidomolybdenum hydrazone complex; cyclohexane oxidation mononuclear dioxidomolybdenum hydrazone complex catalyst.They researched the compound: Bis(acetylacetonato)dioxomolybdenum(VI)( cas:17524-05-9 ).Name: Bis(acetylacetonato)dioxomolybdenum(VI). Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:17524-05-9) here.

Three new dioxomolybdenum (VI) complexes, [MoO2L1(MeOH)] (1), [MoO2L2(MeOH)] (2) and [MoO2L3(H2O)]·EtOH (3), where L1, L2 and L3 are the dianionic form of N’-(2-hydroxybenzylidene)-3-methylbenzohydrazide, 4-bromo-N’-(2-hydroxybenzylidene)benzohydrazide and 2-bromo-N’-(2-hydroxy benzylidene)benzohydrazide, resp., were prepared and characterized by IR, UV-visible and NMR spectra, as well as single crystal x-ray diffraction. The Mo atoms in the complexes are in octahedral coordination, with the ONO donor set of the hydrazone ligands, O atoms of the solvents, and two oxo groups. Crystals of the complexes are stabilized by hydrogen bonds of types O-H···N and O-H···O. Moreover, the catalytic properties of complexes 1-3 are compared in cyclohexane oxidation Sebacic acid and FeCl3 could promote the catalytic activities of the complexes.

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Reference:
Nitrile – Wikipedia,
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In general, if the atoms that make up the ring contain heteroatoms, such rings become heterocycles, and organic compounds containing heterocycles are called heterocyclic compounds. An article called Synthesis, spectroscopic characterization and quantum chemical studies of a dioxomolybdenum(VI) complex with an N,S-substituted pyridoxal thiosemicarbazone, published in 2021-01-01, which mentions a compound: 17524-05-9, Name is Bis(acetylacetonato)dioxomolybdenum(VI), Molecular C10H14MoO6, Related Products of 17524-05-9.

The new compounds Pyridoxal N-allyl-S-methylthiosemicarbazone (L) and the dioxomolybdenum(VI) complex [MoO2(L)CH3OH] have been synthesized and characterized by elemental anal., UV-Vis, FT-IR, Raman and 1H NMR spectra, and also by the single crystal X-ray diffraction technique. Single crystals of the cis-dioxomolybdenum(VI) complex were obtained by evaporating its methanol solution According to the single-crystal X-ray diffraction investigation, the molybdenum atom in the complex is in a distorted octahedral coordination. The sixth coordination site is occupied by the oxygen atom of a methanol solvent mol. The methanol coordination between the oxygen and molybdenum atoms is the weakest bond, with a Mo-O bond length of 2.355 Å. The geometries and vibrational spectra of the pyridoxal thiosemicarbazone (L) and its complex are explained by quantum chem. calculations

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Nitrile – Wikipedia,
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Li, Junfang; Bai, Hua; Zhai, Junfeng; Li, Wentao; Fan, Wenhao; Xi, Guangcheng published the article 《Metallic and plasmonic MoO2 monocrystalline ultrathin mesoporous nanosheets for highly sensitive and stable surface-enhanced Raman spectroscopy》. Keywords: molybdenum dioxide monocrystalline ultrathin mesoporous nanosheet Raman spectrum.They researched the compound: Bis(acetylacetonato)dioxomolybdenum(VI)( cas:17524-05-9 ).Recommanded Product: Bis(acetylacetonato)dioxomolybdenum(VI). Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:17524-05-9) here.

Structure and size control are always considered as effective routes to enhance sensitive performance. Different from common polycrystalline porous nanosheets, herein, the general synthesis of monocrystalline ultrathin porous nanosheets (MUPNSs) by a facile decompressing decomposition (DPD) route is reported. Accompanied with the properties inherited from MUPNSs, i.e., high adsorption and strong plasma resonance, these MoO2 MUPNSs presented high sensitive activity as a surface enhanced Raman spectrum (SERS) substrate. The SERS sensitivity of MoO2 MUPNSs was about 1000 times higher than MoO2 polycrystalline ultrathin porous nanosheets (PUPNSs).

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Reference:
Nitrile – Wikipedia,
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Reference of Bis(acetylacetonato)dioxomolybdenum(VI). The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: Bis(acetylacetonato)dioxomolybdenum(VI), is researched, Molecular C10H14MoO6, CAS is 17524-05-9, about Biodegradation-Mediated Enzymatic Activity-Tunable Molybdenum Oxide Nanourchins for Tumor-Specific Cascade Catalytic Therapy. Author is Hu, Xi; Li, Fangyuan; Xia, Fan; Guo, Xia; Wang, Nan; Liang, Lili; Yang, Bo; Fan, Kelong; Yan, Xiyun; Ling, Daishun.

Recent advances in nanomedicine have facilitated the development of potent nanomaterials with intrinsic enzyme-like activities (nanozymes) for cancer therapy. However, it remains a great challenge to fabricate smart nanozymes that precisely perform enzymic activity in tumor microenvironment without inducing off-target toxicity to surrounding normal tissues. Herein, we report on designed fabrication of biodegradation-medicated enzymic activity-tunable molybdenum oxide nanourchins (MoO3-x NUs), which selectively perform therapeutic activity in tumor microenvironment via cascade catalytic reactions, while keeping normal tissues unharmed due to their responsive biodegradation in physiol. environment. Specifically, the MoO3-x NUs first induce catalase (CAT)-like reactivity to decompose hydrogen peroxide (H2O2) in tumor microenvironment, producing a considerable amount of O2 for subsequent oxidase (OXD)-like reactivity of MoO3-x NUs; a substantial cytotoxic superoxide radical (·O2-) is thus generated for tumor cell apoptosis. Interestingly, once exposed to neutral blood or normal tissues, MoO3-x NUs rapidly lose the enzymic activity via pH-responsive biodegradation and are excreted in urine, thus ultimately ensuring safety. The current study demonstrates a proof of concept of biodegradation-medicated in vivo catalytic activity-tunable nanozymes for tumor-specific cascade catalytic therapy with minimal off-target toxicity.

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