Tag: M.W=300-400

Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 17524-05-9, is researched, Molecular C10H14MoO6, about An insight into the potent antioxidant activity of a dithiocarbohydrazone appended cis-dioxidomolybdenum (VI) complexes, the main research direction is crystal structure oxomolybdenum dithiocarbohydrazone methanol DMSO aqua complex; oxomolybdenum dithiocarbohydrazone preparation antioxidant mol docking enzyme 3MNG.Formula: C10H14MoO6.

In search of antioxidants with enriched potency, the present study focus on the design and synthesis of a dithiocarbohydrazone, H3TCL derived from thiocarbohydrazide and 3-ethoxysalicylaldehyde and its coordination complexes with Mo, viz, [MoO2(HTCL)D] (D = MeOH 1, DMSO 2) and [MoO2(HTCL)D]·DMF (D = H2O 3). The synthesized compounds were characterized by elemental anal., spectroscopic techniques (FTIR, UV-visible and 1H-NMR), conductivity measurements and cyclic voltammetry. Also the solid state structures of all the three complexes were established by single crystal x-ray diffraction anal. as mononuclear neutral species in which the Mo center assumes a distorted octahedral geometry. The dithiocarbohydrazone binds to the Mo center through its phenolate O, O(1), azomethine N, N(1) and thioenolate S, S(1) in a dianionic tridentate mode. The assessment of intermol. contacts in the crystal arrangement was quantified using Hirshfeld surface anal. Further the antioxidant potential of the dithiocarbohydrazone, H3TCL and its Mo complexes 1-3 were evaluated using 1,1-diphenyl-2-picrylhydrazyl(DPPH), 2,2′-azinobis-3-ethylbenzothiazoline-6-sulfonic acid (ABTS) and total antioxidant assays. The antioxidant activities were then compared with standard antioxidant, L-ascorbic acid. The antioxidant potential of the synthesized compounds were then validated by mol. docking studies. Mol. modeling study was achieved to evaluate the recognition of target compound at the binding pocket of the human antioxidant enzyme, 3MNG. The docking results showed that the complexes selectively bond to the vital amino acids present in the binding pocket of the target enzyme, 3MNG.

Different reactions of this compound(Bis(acetylacetonato)dioxomolybdenum(VI))Formula: C10H14MoO6 require different conditions, so the reaction conditions are very important.

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The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: Bis(acetylacetonato)dioxomolybdenum(VI)(SMILESS: O=[Mo+2]12(O=C([CH-]C(C)=O1)C)(O=C([CH-]C(C)=O2)C)=O,cas:17524-05-9) is researched.Formula: C21H16N2. The article 《Impact of morphology on the oxygen evolution reaction of 3D hollow Cobalt-Molybdenum Nitride》 in relation to this compound, is published in Applied Catalysis, B: Environmental. Let’s take a look at the latest research on this compound (cas:17524-05-9).

The oxygen evolution reaction (OER) is an essential process for water electrolysis and to realize the scalability of renewable energy sources. In this work, a strategy is developed to fabricate anisotropic metallic Cobalt-Molybdenum Nitride materials combining hollow 3D structures and 2D nanosheets which result highly active OER electrocatalysts. The sample structure and morphol. is investigated to derive its formation process following the synthesis strategy relying on the ligand-metal interactions of metal-organic framework (ZIF-67 and Mo-aMOF). Three different sample morphologies with large sp. surface areas are obtained by changing the water and 2-methylimidazole contents. After ammonification in NH3, the morphologies and the sp. surface areas of the samples are preserved. The electronic structure can also be adjusted to regulate electron d. of Co and Mo by N-doping. These Co-Mo binary metals offer a viable way for realizing the electronic transfer between the different components, as demonstrated by XPS. Taking advantage from the above features, the as-obtained electrocatalyst exhibits a high catalytic activity and long-term cyclic stability for OER with low overpotential (η10 is 294 mV).

《Impact of morphology on the oxygen evolution reaction of 3D hollow Cobalt-Molybdenum Nitride》 provides a strategy for the preparation of materials with excellent comprehensive properties, which is conducive to broaden the application field of this compound(Bis(acetylacetonato)dioxomolybdenum(VI))Product Details of 17524-05-9.

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The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: Bis(acetylacetonato)dioxomolybdenum(VI)(SMILESS: O=[Mo+2]12(O=C([CH-]C(C)=O1)C)(O=C([CH-]C(C)=O2)C)=O,cas:17524-05-9) is researched.Computed Properties of C21H16N2. The article 《Insights into the Structure-Activity Relationship in Aerobic Alcohol Oxidation over a Metal-Organic-Framework-Supported Molybdenum(VI) Catalyst》 in relation to this compound, is published in Journal of the American Chemical Society. Let’s take a look at the latest research on this compound (cas:17524-05-9).

The understanding of structure-activity relations at the at. level has played a profound role in heterogeneous catalysis, providing valuable insights into designing suitable heterogeneous catalysts. However, uncovering the detailed roles of how such active species’ structures affect their catalytic performance remains a challenge owing to the lack of direct structural information on a specific active species. Herein, the authors deposited molybdenum(VI), an active species in oxidation reactions, on the Zr6 node of a mesoporous zirconium-based metal-organic framework (MOF) NU-1200, using solvothermal deposition in MOFs (SIM). Due to the high crystallinity of the NU-1200 support, the precise structure of the resulting molybdenum catalyst, Mo-NU-1200, was characterized through single-crystal x-ray diffraction (SCXRD). Two distinct anchoring modes of the molybdenum species were observed: one mode (Mo1), displaying an octahedral geometry, coordinated to the node through one terminal oxygen atom and the other mode (Mo2) coordinated to two adjacent Zr6 node oxygen atoms in a tetrahedral geometry. To investigate the role of base in the catalytic activity of these Mo centers, the authors assessed the activity of Mo-NU-1200 for the aerobic oxidation of 4-methoxybenzyl alc. as a model reaction. Mo-NU-1200 exhibited remarkably higher catalytic reactivity under base-free conditions, while the presence of base inhibited the catalytic reactivity of this species. SCXRD studies revealed that the molybdenum binding motifs (structures of the supported metal on the Zr6 node in the MOF) changed over the reactions. Following the oxidation without base, both pristine coordination modes (Mo1 and Mo2) evolved into a new coordination mode (Mo3), in which the molybdenum atom coordinated to two adjacent oxygen atoms from the Zr6 node in an octahedral geometry, while in the presence of base, the pristine Mo1 coordination mode evolved entirely into the pristine Mo2. This study demonstrates the direct observation of an active species’ structural evolution from metal installation to subsequent catalytic reaction. As a result, these subtle structural changes in catalyst binding motifs led to distinct differences in catalytic activities, providing a compelling strategy for elucidating structure-activity relations.

《Insights into the Structure-Activity Relationship in Aerobic Alcohol Oxidation over a Metal-Organic-Framework-Supported Molybdenum(VI) Catalyst》 provides a strategy for the preparation of materials with excellent comprehensive properties, which is conducive to broaden the application field of this compound(Bis(acetylacetonato)dioxomolybdenum(VI))Electric Literature of C10H14MoO6.

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In general, if the atoms that make up the ring contain heteroatoms, such rings become heterocycles, and organic compounds containing heterocycles are called heterocyclic compounds. An article called SBA-16 supported amino acid Schiff base complexes of molybdenum as new heterogeneous molybdenum catalysts, published in 2019-06-05, which mentions a compound: 17524-05-9, Name is Bis(acetylacetonato)dioxomolybdenum(VI), Molecular C10H14MoO6, Safety of Bis(acetylacetonato)dioxomolybdenum(VI).

Immobilization of molybdenum complexes of amino acid Schiff bases within the SBA-16 nanocages produced new heterogeneous catalysts for the epoxidation of olefins. First, amino acid Schiff bases were obtained through the reaction of amino acids with salicylaldehyde. Then, complexation of the prepared amino acid Schiff bases with molybdenum (VI) produced the molybdenum complexes of amino acid Schiff bases. Immobilization of the molybdenum complexes into the SBA-16 nanocages followed by silylation with triethoxyoctylsilane gave the heterogenized molybdenum catalysts. The obtained catalysts were characterized with several physicochem. techniques. FT-IR and inductively coupled plasma optical emission (ICP-OES) spectroscopies approved the inclusion of molybdenum complexes within the SBA-16 nanocages. The results of X-ray diffraction (XRD) and nitrogen adsorption-desorption (BET method) analyses illustrated that surface properties of SBA-16 were maintained upon the inclusion of molybdenum complexes. The prepared catalysts exhibited good activities and excellent selectivities (>99%) in the epoxidation of olefins with tert-Bu hydroperoxide (TBHP).

《SBA-16 supported amino acid Schiff base complexes of molybdenum as new heterogeneous molybdenum catalysts》 provides a strategy for the preparation of materials with excellent comprehensive properties, which is conducive to broaden the application field of this compound(Bis(acetylacetonato)dioxomolybdenum(VI))Safety of Bis(acetylacetonato)dioxomolybdenum(VI).

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Nitrile – Wikipedia,
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Titova, N.; Gayduchenko, I. A.; Moskotin, M. V.; Fedorov, G. F.; Goltsman, G. N. published the article 《Carbon nanotube based terahertz radiation detectors》. Keywords: carbon nanotube radiation detector.They researched the compound: Bis(acetylacetonato)dioxomolybdenum(VI)( cas:17524-05-9 ).Quality Control of Bis(acetylacetonato)dioxomolybdenum(VI). Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:17524-05-9) here.

In this paper, we study terahertz detectors based on single quasimetallic carbon nanotubes (CNT) with asym. contacts and different metal pairs. We demonstrate that, depending on the contact metalization of the device, various detection mechanisms are manifested.

The article 《Carbon nanotube based terahertz radiation detectors》 also mentions many details about this compound(17524-05-9)Quality Control of Bis(acetylacetonato)dioxomolybdenum(VI), you can pay attention to it, because details determine success or failure

Reference:
Nitrile – Wikipedia,
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The preparation of ester heterocycles mostly uses heteroatoms as nucleophilic sites, which are achieved by intramolecular substitution or addition reactions. Compound: Bis(acetylacetonato)dioxomolybdenum(VI)( cas:17524-05-9 ) is researched.Computed Properties of C10H14MoO6.Polo, Annalisa; Nomellini, Chiara; Grigioni, Ivan; Dozzi, Maria Vittoria; Selli, Elena published the article 《Effective Visible Light Exploitation by Copper Molybdo-tungstate Photoanodes》 about this compound( cas:17524-05-9 ) in ACS Applied Energy Materials. Keywords: copper molybdenum tungstate photoanode light exploitation. Let’s learn more about this compound (cas:17524-05-9).

The need for stable oxide-based semiconductors with a narrow band gap, able to maximize the exploitation of the visible light portion of the solar spectrum, is a challenging issue for photoelectrocatalytic (PEC) applications. In the present work, CuW1-xMoxO4 (Eg = 2.0 eV for x = 0.5), which exhibits a significantly reduced optical band gap Eg compared with isostructural CuWO4 (Eg = 2.3 eV), was investigated as a photoactive material for the preparation of photoanodes. CuW0.5Mo0.5O4 electrodes with different thicknesses (80-530 nm), prepared by a simple solution-based process in the form of multilayer films, effectively exhibit visible light photoactivity up to 650 nm (i.e., extended compared with CuWO4 photoanodes prepared by the same way). Furthermore, the systematic investigation on the effects on photoactivity of the CuW0.5Mo0.5O4 layer thickness evidenced that long-wavelength photons can better be exploited by thicker electrodes. PEC measurements in the presence of NaNO2, acting as a suitable hole scavenger ensuring enhanced photocurrent generation compared with that of water oxidation while minimizing dark currents, allowed us to elucidate the role that molybdenum incorporation plays on the charge separation efficiency in the bulk and on the charge injection efficiency at the photoanode surface. The adopted Mo for W substitution increases the visible light photoactivity of copper tungstate toward improved exploitation and storage of visible light into chem. energy via photoelectrocatalysis.

The article 《Effective Visible Light Exploitation by Copper Molybdo-tungstate Photoanodes》 also mentions many details about this compound(17524-05-9)Computed Properties of C10H14MoO6, you can pay attention to it, because details determine success or failure

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Nitrile – Wikipedia,
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Formula: C10H14MoO6. Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: Bis(acetylacetonato)dioxomolybdenum(VI), is researched, Molecular C10H14MoO6, CAS is 17524-05-9, about Post modification of zinc based coordination polymer to prepare Zn-Mo-ICP nanoparticles as efficient self-supported catalyst for olefin epoxidation. Author is Mohammadikish, Maryam; Yarahmadi, Sana.

Preparation, characterization, and catalytic properties of bimetallic coordination polymer constructed from 2-aminoterephthalic acid as linker, zinc cations as node, and cis-dioxo molybdenum units as catalytic active sites are reported via two pathways. Molybdenum centers were placed in N,O positions created by condensation reaction of 2-aminoterephthalic acid with salicylaldehyde while zinc cations coordinated via carboxylic acid groups of linker to achieve infinite chains of metalo-ligand. The obtained coordination polymer was fully characterized and its catalytic properties in the epoxidation of olefins with tert-Bu hydroperoxide (TBHP) described. In comparison with previously reported heterogenized molybdenum catalysts, this new coordination polymer exhibited good conversion as well as high selectivity in the epoxidation of olefins. The catalyst is stable under ambient conditions and could be reused as active catalyst for at least five times.

The article 《Post modification of zinc based coordination polymer to prepare Zn-Mo-ICP nanoparticles as efficient self-supported catalyst for olefin epoxidation》 also mentions many details about this compound(17524-05-9)Formula: C10H14MoO6, you can pay attention to it, because details determine success or failure

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The reaction of an aromatic heterocycle with a proton is called a protonation. One of articles about this theory is 《Two new hydrogen-bonded supramolecular dioxo-molybdenum(VI) complexes based on acetyl-hydrazone ligands: Synthesis, crystal structure and DFT studies》. Authors are Maiti, Monami; Thakurta, Santarupa; Pilet, Guillaume; Bauza, Antonio; Frontera, Antonio.The article about the compound:Bis(acetylacetonato)dioxomolybdenum(VI)cas:17524-05-9,SMILESS:O=[Mo+2]12(O=C([CH-]C(C)=O1)C)(O=C([CH-]C(C)=O2)C)=O).Formula: C10H14MoO6. Through the article, more information about this compound (cas:17524-05-9) is conveyed.

Two new cis-dioxomolybdenum(VI) complexes [MoO2L1(H2O)] (1) and [MoO2L2(H2O)] (2) were synthesized using two different tridentate hydrazone Schiff base ligands, L1H2 [(E)-N’-(2-hydroxybenzylidene)acetohydrazide] and L2H2 [(E)-N’-(2-hydroxy-3-methoxybenzylidene)acetohydrazide], resp. The ligands and their corresponding Mo complexes are thoroughly characterized by different physicochem. techniques. Mol. structures of the complexes were conclusively accomplished by single crystal x-ray diffraction. Both complexes have a distorted octahedral geometry around the Mo(VI) center. The tridentate hydrazones coordinate to the metal centers in their enolic form in both 1 and 2. H bonding and π-π interactions play an important role in the packing of the complexes in their solid state. Computational studies are also performed using DFT calculations at BP86-D3/def2-TZVP level of theory to understand the relative stability of the supramol. networks.

The article 《Two new hydrogen-bonded supramolecular dioxo-molybdenum(VI) complexes based on acetyl-hydrazone ligands: Synthesis, crystal structure and DFT studies》 also mentions many details about this compound(17524-05-9)Formula: C10H14MoO6, you can pay attention to it, because details determine success or failure

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Most of the compounds have physiologically active properties, and their biological properties are often attributed to the heteroatoms contained in their molecules, and most of these heteroatoms also appear in cyclic structures. A Journal, Journal of Molecular Structure called Synthesis, crystal structure and Hirshfeld surface analysis of an octa-molybdate, dimethylammonium, (E)-N’-(pyridin-2-ylmethylene)acetohydrazide Co-crystal (1:4:2), Author is Phanimala, C.; Krishna, P. Murali; Reddy, K. Hussain; Kumar, G. N. Anil, which mentions a compound: 17524-05-9, SMILESS is O=[Mo+2]12(O=C([CH-]C(C)=O1)C)(O=C([CH-]C(C)=O2)C)=O, Molecular C10H14MoO6, HPLC of Formula: 17524-05-9.

The co-crystal, Mo8O26 2(C8H9N3O)·4(C2H8N) consists of Octamolybdate, (Mo8O26)-4 an anionic cluster surrounded by four dimethylammonium ions (C2H8N)+ and (E)-N’-(pyridin-2-ylmethylene)acetohydrazide 2(C8H9N3O) was synthesized and characterized by FTIR and UV-visible spectroscopic methods. Single crystal x-ray diffraction anal. reveals that complex (C24H50Mo8N10O28) contains, Octamolybdate, (Mo8O26)4- an anionic cluster surrounded by four dimethylammonium ions (C2H8N)+ along with (E)-N’-(pyridin-2-ylmethylene)acetohydrazide 2(C8H9N3O), in the unit cell. Further N’-[(E)-pyridin-2-ylmethylene]acetohydrazide mols. holding the octa-molybdate units forming three dimensional supramol. networks through number of C-H···O and N-H ··· O interactions. The Hirshfeld surfaces and two-dimensional fingerprint plots were generated to visualize the intermol. interactions quant. for their relative contributions.

The article 《Synthesis, crystal structure and Hirshfeld surface analysis of an octa-molybdate, dimethylammonium, (E)-N’-(pyridin-2-ylmethylene)acetohydrazide Co-crystal (1:4:2)》 also mentions many details about this compound(17524-05-9)HPLC of Formula: 17524-05-9, you can pay attention to it, because details determine success or failure

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Ehsan, Muhammad Ali; Khan, Abuzar published the article 《Aerosol-Assisted Chemical Vapor Deposition Growth of NiMoO4 Nanoflowers on Nickel Foam as Effective Electrocatalysts toward Water Oxidation》. Keywords: molybdenum oxide nanoflower nickel foam electrocatalyst water oxidation.They researched the compound: Bis(acetylacetonato)dioxomolybdenum(VI)( cas:17524-05-9 ).Recommanded Product: 17524-05-9. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:17524-05-9) here.

The fabrication of active and durable catalysts derived from transition metals is highly desired for the realization of efficient water oxidation reactions. This is particularly important to address the slow oxygen evolution reaction (OER) kinetics and hence can contribute to the conversion and storage of sustainable energy. In this study, the deposition of crystalline flowerlike 2D nanosheets of nickel molybdate (NiMoO4) directly on nickel foam (NF) through an aerosol-assisted chem. vapor deposition process is reported. The NiMoO4 nanosheets were developed on NF by altering the deposition time for 60 and 120 min at a fixed temperature of 480°C. The structural determination by XRD and XPS analyses revealed a highly crystalline single phase NiMoO4. The micrographs of NiMoO4 show that the surface consisted of vertically aligned 2D nanosheets assembled into flowerlike structures. The nanosheets produced after 60 min deposition time on a network of NF is found to perform better for OER as compared to the one developed for 120 min. A reference c.d. of 10 mA cm-2 was achieved at an overpotential (η) of 320 mV, which was better as compared to that reported for the benchmark OER catalyst in 1.0 M KOH. Moreover, a small Tafel value (75 mV dec-1) and good OER stability for >15 h were also observed

Different reactions of this compound(Bis(acetylacetonato)dioxomolybdenum(VI))Recommanded Product: 17524-05-9 require different conditions, so the reaction conditions are very important.

Reference:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts