Category: 7528-78-1

Zakirov, N. S. et al. published their research in Zhurnal Analiticheskoi Khimii in 1987 | CAS: 7528-78-1

3,3′,3”-Nitrilotripropanenitrile (cas: 7528-78-1) belongs to nitriles. Nitrile compounds can be prepared by the incorporation of a cyanide source through C–C bond formation or by dehydration of primary carboxamides. Some nitriles are manufactured by heating carboxylic acids with ammonia in the presence of catalysts. This process is used to make nitriles from natural fats and oils, the products being used as softening agents in synthetic rubbers, plastics, and textiles and for making amines.Formula: C9H12N4

Use of the least squares method for estimating the sorption capability of cyano-group-containing phases in gas chromatography was written by Zakirov, N. S.. And the article was included in Zhurnal Analiticheskoi Khimii in 1987.Formula: C9H12N4 This article mentions the following:

The least squares method was used for quant. estimation of the sorption capability of cyano-group containing stationary phases in gas chromatog. separation of alcs., nitriles, and hydrocarbons. The method can be used for selection and optimization of stationary phases with respect to analyte chain length. In the experiment, the researchers used many compounds, for example, 3,3′,3”-Nitrilotripropanenitrile (cas: 7528-78-1Formula: C9H12N4).

3,3′,3”-Nitrilotripropanenitrile (cas: 7528-78-1) belongs to nitriles. Nitrile compounds can be prepared by the incorporation of a cyanide source through C–C bond formation or by dehydration of primary carboxamides. Some nitriles are manufactured by heating carboxylic acids with ammonia in the presence of catalysts. This process is used to make nitriles from natural fats and oils, the products being used as softening agents in synthetic rubbers, plastics, and textiles and for making amines.Formula: C9H12N4

Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts

Kim, Youngwon et al. published their research in Comptes Rendus Chimie in 2016 | CAS: 7528-78-1

3,3′,3”-Nitrilotripropanenitrile (cas: 7528-78-1) belongs to nitriles. The electronic structure of nitriles is very similar to that of an alkyne with the main difference being the presence of a set of lone pair electrons on the nitrogen. Nitrile groups in organic compounds can undergo a variety of reactions depending on the reactants or conditions. A nitrile group can be hydrolyzed, reduced, or ejected from a molecule as a cyanide ion.Recommanded Product: 3,3′,3”-Nitrilotripropanenitrile

Parent-amido (NH2) palladium(II) complexes: Synthesis, reactions, and catalytic hydroamination was written by Kim, Youngwon;Park, Soonheum. And the article was included in Comptes Rendus Chimie in 2016.Recommanded Product: 3,3′,3”-Nitrilotripropanenitrile This article mentions the following:

The treatment of [PdL3(NH3)](OTf)n [n = 1; L3 = (PEt3)2(Ph), 2,6-(Cy2PCH2)2C6H3; n = 2; L3 = (dppe)(NH3)] with NaNH2 in THF at ambient temperature or -78鎺?afforded the dimeric and monomeric parent-amido palladium(II) complexes anti-[Pd(PEt3)(Ph)(娓?NH2)]2 (1), [Pd(dppe)(娓?NH2)]2(OTf)2 (2), and Pd(2,6-(Cy2PCH2)2C6H3)(NH2) (3), resp. The mol. structures of the amido-bridged (娓?NH2) dimeric complexes 1 and 2 were determined by single-crystal x-ray crystallog. The monomeric amido complex 3 reacted with trace amounts of water to give a hydroxo complex, Pd(2,6-(Cy2PCH2)2C6H3)(OH) (4). Exposing complex 3 to an excess of water resulted in the complete conversion of the complex into two species [Pd(2,6-(Cy2PCH2)2C6H3)(OH2)]+ and [Pd(2,6-(Cy2PCH2)2C6H3)(NH3)]+. Complex 3 reacted with diphenyliodonium triflate ([Ph2I]OTf) to give the aniline complex [Pd(2,6-(Cy2PCH2)2C6H3)(NH2Ph)]OTf. The reaction of 3 with phenylacetylene (HC椤氬挵Ph) yielded a palladium(II) acetylenide Pd(2,6-(Cy2PCH2)2C6H3)(C椤氬挵Ph) (5), quant., along with the liberation of ammonia. The reaction of 3 with dialkyl acetylenedicarboxylate yielded diastereospecific palladium(II) vinyl derivatives (Z)-[Pd(2,6-(Cy2PCH2)2C6H3)(CR:CRNH2)] (6a,b, R = CO2Me, CO2Et). The reaction of complexes 6a and 6b with p-nitrophenol produced Pd(2,6-(Cy2PCH2)2C6H3)(OC6H4-p-NO2) (7) and cis-CHR:CR(NH2), exclusively. Reactions of 3 with either dialkyl maleate cis-(CO2R)CH=CH(CO2R) (R = Me, Et) or cis-stilbene cis-CHPh:CHPh did not result in any addition product. Instead, isomerization of the cis-isomers to the trans-isomers occurred in the presence of catalytic amounts of 3. Complex 3 reacted with a stoichiometric amount of acrylonitrile CH2:CHCN to generate a metastable insertion product, Pd(2,6-(Cy2PCH2)2C6H3)(CH(CN)CH2NH2). On the other hand, the reaction of 3 with an excess of acrylonitrile slowly produced polymeric species of acrylonitrile. The catalytic hydroamination of olefins with NH3 was examined in the presence of Pd(2,6-(Cy2PCH2)2C6H3)(OTf), producing a range of hydroaminated products of primary, secondary, and tertiary amines with different molar ratios of more than 99% overall yield. A mechanistic feature for the observed catalytic hydroamination is described with regard to the aminated derivatives of palladium(II). In the experiment, the researchers used many compounds, for example, 3,3′,3”-Nitrilotripropanenitrile (cas: 7528-78-1Recommanded Product: 3,3′,3”-Nitrilotripropanenitrile).

3,3′,3”-Nitrilotripropanenitrile (cas: 7528-78-1) belongs to nitriles. The electronic structure of nitriles is very similar to that of an alkyne with the main difference being the presence of a set of lone pair electrons on the nitrogen. Nitrile groups in organic compounds can undergo a variety of reactions depending on the reactants or conditions. A nitrile group can be hydrolyzed, reduced, or ejected from a molecule as a cyanide ion.Recommanded Product: 3,3′,3”-Nitrilotripropanenitrile

Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts