Clive, Derrick L. J. published the artcileThe Naturally Occurring Ketene Acetal Benesudon: Total Synthesis and Assignment of Relative and Absolute Stereochemistry, Product Details of C6H7NO, the main research area is asym synthesis ketene acetal benesudon radical cyclization oxidative decarboxylation; mol structure absolute configuration benesudon.
The densely functionalized ketene acetal benesudon (I), which is a bioactive fungal metabolite, was synthesized from D-glucose by a route involving radical cyclization to form the five-membered ring, and oxidative decarboxylation to generate the key central double bond. The originally suggested stereochem. for the quaternary center C(5) must be revised, as both C(5) epimers were prepared and a comparison with an authentic sample was made. The absolute configuration of benesudon is 4S,5R,6S.
Journal of Organic Chemistry published new progress about Absolute configuration. 31518-13-5 belongs to class nitriles-buliding-blocks, name is 3,4-Dihydro-2H-pyran-6-carbonitrile, and the molecular formula is C6H7NO, Product Details of C6H7NO.
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts