Category: 16144-65-3

Electrochemical oxidation of organic compounds in fluorosulfuric acid. VIII. Current-voltage characteristics of the oxidation of aromatic compounds in fluorosulfuric acid and acetonitrile was written by Rudenko, A. P.;Zarubin, M. Ya.;Pragst, Fritz. And the article was included in Zhurnal Organicheskoi Khimii in 1984.Category: nitriles-buliding-blocks The following contents are mentioned in the article:

Cyclic voltammograms were obtained for the oxidation of polysubstituted benzenes and diphenylmethanes containing electron-withdrawing groups (e.g., SO₂F, NO₂, CN, CO₂H) in HSO₃F and MeCN. In most cases the oxidation in HSO₃F leads reversibly to the cation radical at low rates of potential scanning; in MeCN the process is irreversible even at high scanning rates (up to 100 V/s). This study involved multiple reactions and reactants, such as 2,2′,2”-(2,4,6-Trimethylbenzene-1,3,5-triyl)triacetonitrile (cas: 16144-65-3Category: nitriles-buliding-blocks).

2,2′,2”-(2,4,6-Trimethylbenzene-1,3,5-triyl)triacetonitrile (cas: 16144-65-3) belongs to nitriles. Nitrile compounds can be prepared by the incorporation of a cyanide source through C–C bond formation or by dehydration of primary carboxamides. Asymmetric bioreduction of nitriles is an attractive route to produce optically active nitriles as current metal-catalyzed hydrogenations tend to have low reactivity.Category: nitriles-buliding-blocks

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Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts

Synthesis of C₁-symmetric chiral tripodal oxazolines through an oxazoline exchange reaction with amino alcohols was written by Kim, Sung-Gon;Seong, Hye Ran;Kim, Jeongryul;Ahn, Kyo Han. And the article was included in Tetrahedron Letters in 2004.Category: nitriles-buliding-blocks The following contents are mentioned in the article:

Various C₁-sym. chiral tripodal tris(oxazolines), e.g., I, with two different oxazoline units were synthesized from chiral C₃-sym. tris(oxazolines) through an oxazoline exchange reaction with amino alcs. in the presence of zinc chloride. Evaluation of the oxazolines as chiral mol. receptor showed that some of the receptors have chiral discrimination ability. This study involved multiple reactions and reactants, such as 2,2′,2”-(2,4,6-Trimethylbenzene-1,3,5-triyl)triacetonitrile (cas: 16144-65-3Category: nitriles-buliding-blocks).

2,2′,2”-(2,4,6-Trimethylbenzene-1,3,5-triyl)triacetonitrile (cas: 16144-65-3) belongs to nitriles. Nitrile function is a very important functional group because it can be manipulated to other functional groups such as carboxylic acid by hydrolysis or amine by reduction, respectively. Industrially, the main methods for producing nitriles are ammoxidation and hydrocyanation. Both routes are green in the sense that they do not generate stoichiometric amounts of salts.Category: nitriles-buliding-blocks

Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts

Topological correspondence between crystal structure of 2,4,6-trimethylbenzene-1,3,5-tris(methanaminium) 2,4,6-trimethylbenzene-1,3,5-triacetate and cesium chloride was written by Podlaha, Jaroslav;Cisarova, Ivana;Alexander, Daniel;Holy, Petr;Kraus, Tomas;Zavada, Jiri. And the article was included in Collection of Czechoslovak Chemical Communications in 2000.HPLC of Formula: 16144-65-3 The following contents are mentioned in the article:

Solid-state self-assembly of 2,4,6-trimethylbenzene-1,3,5-tris(methanaminium) 2,4,6-trimethylbenzene-1,3,5-triacetate is mediated by hydrogen bonding. It gives rise to three-dimensional network of hydrogen bonds in which each trication is coordinated with eight trianions and vice versa. The resulting crystal structure topol. corresponds to the simple inorganic cesium chloride type. This study involved multiple reactions and reactants, such as 2,2′,2”-(2,4,6-Trimethylbenzene-1,3,5-triyl)triacetonitrile (cas: 16144-65-3HPLC of Formula: 16144-65-3).

2,2′,2”-(2,4,6-Trimethylbenzene-1,3,5-triyl)triacetonitrile (cas: 16144-65-3) belongs to nitriles. Nitrile function is a very important functional group because it can be manipulated to other functional groups such as carboxylic acid by hydrolysis or amine by reduction, respectively. In conventional organic reductions, nitrile is reduced by treatment with lithium aluminium hydride to the amine. Reduction to the imine followed by hydrolysis to the aldehyde takes place in the Stephen aldehyde synthesis, which uses stannous chloride in acid.HPLC of Formula: 16144-65-3

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Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts

Oxidation of hexamethylbenzene and 2,3,4,5,6-pentamethylbenzyl cation in fluorosulfonic acid was written by Rudenko, A. P.;Zarubin, M. Ya.;Fedorova, E. M.. And the article was included in Zhurnal Organicheskoi Khimii in 1985.Synthetic Route of C15H15N3 The following contents are mentioned in the article:

Oxidation of hexamethylbenzene (I) in HSO₃F-PbO₂ involved the conversion of protonated I to 2,3,4,5,6-pentamethylbenzyl cation, which underwent further oxidation to give products such as II and III. This study involved multiple reactions and reactants, such as 2,2′,2”-(2,4,6-Trimethylbenzene-1,3,5-triyl)triacetonitrile (cas: 16144-65-3Synthetic Route of C15H15N3).

2,2′,2”-(2,4,6-Trimethylbenzene-1,3,5-triyl)triacetonitrile (cas: 16144-65-3) belongs to nitriles. Nitrile carbon shifts are in the range of 115–125 ppm whereas in isonitriles the shifts are around 155–165 ppm. In addition, Nitriles can react with alkynes, which leads to an increase in carbon chain length (carbocyanation).Synthetic Route of C15H15N3

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Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts

Selective recognition of NH₄⁺ over K⁺ with tripodal oxazoline receptors was written by Ahn, Kyo Han;Kim, Sung-Gon;Jung, Junyang;Kim, Kyung-Hyun;Kim, Jaheon;Chin, Jik;Kim, Kimoon. And the article was included in Chemistry Letters in 2000.Application In Synthesis of 2,2′,2”-(2,4,6-Trimethylbenzene-1,3,5-triyl)triacetonitrile The following contents are mentioned in the article:

Benzene-based tripodal tris(oxazolines) are found to be promising receptors for the selective recognition of NH₄⁺ over K⁺ with high binding affinities. This study involved multiple reactions and reactants, such as 2,2′,2”-(2,4,6-Trimethylbenzene-1,3,5-triyl)triacetonitrile (cas: 16144-65-3Application In Synthesis of 2,2′,2”-(2,4,6-Trimethylbenzene-1,3,5-triyl)triacetonitrile).

2,2′,2”-(2,4,6-Trimethylbenzene-1,3,5-triyl)triacetonitrile (cas: 16144-65-3) belongs to nitriles. There has been no report on the microbial biosynthesis of nitriles and the physiological function of such enzymes, nor was it not even known whether aliphatic and aromatic nitriles are biological compounds or just petrochemicals. In conventional organic reductions, nitrile is reduced by treatment with lithium aluminium hydride to the amine. Reduction to the imine followed by hydrolysis to the aldehyde takes place in the Stephen aldehyde synthesis, which uses stannous chloride in acid.Application In Synthesis of 2,2′,2”-(2,4,6-Trimethylbenzene-1,3,5-triyl)triacetonitrile

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Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts

Electrochemical oxidation of organic compounds in fluorosulfuric acid. IV. Voltammetric study of the formation and of the anodic behavior of some benzyl cations and arenium ions was written by Rudenko, A. P.;Zarubin, M. Ya.;Pragst, F.. And the article was included in Journal fuer Praktische Chemie (Leipzig) in 1983.Related Products of 16144-65-3 The following contents are mentioned in the article:

A cyclic voltammetric study of the oxidation of benzylic alcs., ethers, acetates, and cyanides and of aromatic hydrocarbons in FSO₃H at -76° was reported. Benzyl cations were oxidized at potentials 0.7-0.8 V more pos. than those of the neutral compounds to [ArCH₂OSO₂F]⁺• cation radicals. In a subsequent step another Me group was functionalized to CH₂OSO₂F. The anodic peak potentials of the arenium ions was ∼1.1 V more pos. than those of the nonprotonated hydrocarbons. The dissociation equilibrium of ArCH₂OSO₂F and the protonation equilibrium of the hydrocarbons were discussed in terms of the donor ability of the aromatic compounds in borderline cases. This study involved multiple reactions and reactants, such as 2,2′,2”-(2,4,6-Trimethylbenzene-1,3,5-triyl)triacetonitrile (cas: 16144-65-3Related Products of 16144-65-3).

2,2′,2”-(2,4,6-Trimethylbenzene-1,3,5-triyl)triacetonitrile (cas: 16144-65-3) belongs to nitriles. Nitrile compounds can be prepared by the incorporation of a cyanide source through C–C bond formation or by dehydration of primary carboxamides. In conventional organic reductions, nitrile is reduced by treatment with lithium aluminium hydride to the amine. Reduction to the imine followed by hydrolysis to the aldehyde takes place in the Stephen aldehyde synthesis, which uses stannous chloride in acid.Related Products of 16144-65-3

Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts

Breaking the C₃-Symmetry of Chiral Tripodal Oxazolines: Enantio-Discrimination of Chiral Organoammonium Ions was written by Kim, Jeongryul;Kim, Sung-Gon;Seong, Hye Ran;Ahn, Kyo Han. And the article was included in Journal of Organic Chemistry in 2005.Safety of 2,2′,2”-(2,4,6-Trimethylbenzene-1,3,5-triyl)triacetonitrile The following contents are mentioned in the article:

A phenylglycinol-derived tripodal oxazoline with C₁-symmetry (C₁-PhBTO) was synthesized, and its enantioselective recognition behavior toward α-chiral primary organoammonium ions was studied. The C₁-PhBTO receptor showed higher selectivity with an opposite sense of enantio-discrimination compared to other C₁-sym. analogs examined but lower selectivity with the same sense of enantioselection compared to its C₃-sym. analog. Binding studies indicated that the C₁-sym. receptors, particularly C₁-PhBTO, interact with the guests in a 2:1 host-guest complex mode in stark contrast to its C₃-sym. analogs. This study involved multiple reactions and reactants, such as 2,2′,2”-(2,4,6-Trimethylbenzene-1,3,5-triyl)triacetonitrile (cas: 16144-65-3Safety of 2,2′,2”-(2,4,6-Trimethylbenzene-1,3,5-triyl)triacetonitrile).

2,2′,2”-(2,4,6-Trimethylbenzene-1,3,5-triyl)triacetonitrile (cas: 16144-65-3) belongs to nitriles. The electronic structure of nitriles is very similar to that of an alkyne with the main difference being the presence of a set of lone pair electrons on the nitrogen. Asymmetric bioreduction of nitriles is an attractive route to produce optically active nitriles as current metal-catalyzed hydrogenations tend to have low reactivity.Safety of 2,2′,2”-(2,4,6-Trimethylbenzene-1,3,5-triyl)triacetonitrile

Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts

Aliphatic polythioamides. I. Synthesis of bis(dithioesters) was written by Gressier, J. C.;Levesque, G.. And the article was included in European Polymer Journal in 1980.Related Products of 16144-65-3 The following contents are mentioned in the article:

Bis(n-dodecyl dithioesters) are prepared by hydrochlorination of dinitriles, e. g., (CH₂)₄(CN)₂, in the presence of thiols followed by sulfuration of the resulting dihydrochlorides, e. g., RSC(:NH)(CH₂)₄C(:NH)SR.2HCl (R = dodecyl). The process gives solid, air-stable products of high purity, which are suitable for polycondensation with aliphatic diamines at low temperature to give high- mol.-weight polythioamides. The tetrathioadipates are degraded in the presence of bases to give a conjugated dithioester, in a reaction comparable with the Dieckmann cyclization of diesters. This study involved multiple reactions and reactants, such as 2,2′,2”-(2,4,6-Trimethylbenzene-1,3,5-triyl)triacetonitrile (cas: 16144-65-3Related Products of 16144-65-3).

2,2′,2”-(2,4,6-Trimethylbenzene-1,3,5-triyl)triacetonitrile (cas: 16144-65-3) belongs to nitriles. Nitrile function is a very important functional group because it can be manipulated to other functional groups such as carboxylic acid by hydrolysis or amine by reduction, respectively. Industrially, the main methods for producing nitriles are ammoxidation and hydrocyanation. Both routes are green in the sense that they do not generate stoichiometric amounts of salts.Related Products of 16144-65-3

Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts

Electrochemical oxidation of organic compounds in fluorosulfuric acid. X. Effect of the increase in acidity on the anodic behavior of some aromatic compounds in the fluorosulfuric acid-antimony pentafluoride system was written by Rudenko, A. P.;Zarubin, M. Ya.;Averyanov, S. F.. And the article was included in Journal fuer Praktische Chemie (Leipzig) in 1985.HPLC of Formula: 16144-65-3 The following contents are mentioned in the article:

The electrochem. oxidation of 37 aromatic compounds (nitriles, nitro compounds, amines, sulfonyl fluorides, carbonyl compounds, hydrocarbons, benzylic acetates, MeO compounds) was examined by cyclic voltammetry in HSO₃F and 15:1 and 3:1 HSO₃F-SbF₅ at -76° and, in some cases, in 1:1 HSO₃F-SbF₅ at -40°. In most cases the half-peak potential underwent a pos. shift as the content of SbF₅ was increased. The anodic behavior also depended on the deprotonation rate of the substrate. This study involved multiple reactions and reactants, such as 2,2′,2”-(2,4,6-Trimethylbenzene-1,3,5-triyl)triacetonitrile (cas: 16144-65-3HPLC of Formula: 16144-65-3).

2,2′,2”-(2,4,6-Trimethylbenzene-1,3,5-triyl)triacetonitrile (cas: 16144-65-3) belongs to nitriles. Nitrile carbon shifts are in the range of 115–125 ppm whereas in isonitriles the shifts are around 155–165 ppm. Some nitriles are manufactured by heating carboxylic acids with ammonia in the presence of catalysts. This process is used to make nitriles from natural fats and oils, the products being used as softening agents in synthetic rubbers, plastics, and textiles and for making amines.HPLC of Formula: 16144-65-3

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Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts

Polar self-assembly: steric effects leading to polar mixed-ligand coordination cages was written by Zhang, Jianyong;Miller, Philip W.;Nieuwenhuyzen, Mark;James, Stuart L.. And the article was included in Chemistry – A European Journal in 2006.Application In Synthesis of 2,2′,2”-(2,4,6-Trimethylbenzene-1,3,5-triyl)triacetonitrile The following contents are mentioned in the article:

The authors present a highly unusual example of self-assembly, specifically a polar, mixed-ligand cage which forms in preference to sym. homoligand products, and which suggests that steric effects can be exploited to obtain novel nonuniform polyhedral cages. In particular, reaction between the bulky tripodal triphosphine 2,4,6-tris(diphenylphosphino)triazine, L1, the nonbulky tripodal trinitrile 2,4,6-tris(cyanomethyl)trimethylbenzene, L2 and AgSbF₆ in a 3:1:4 ratio gives the mixed-ligand aggregate [Ag₄(L1)₃(L2)(SbF₆)]³⁺, 1-SbF₆, instantly as the only product in quant. yield. The x-ray crystal structure of complex 1-SbF₆ is consistent with the suspected solution-state structure. The cage derives from trigonal-pyramidal geometry, the basal vertexes of which are defined by three bulky triphosphines, L1, and the apical vertex by the nonbulky trinitrile, L2. There is apical elongation amounting to 19% in comparison to the ideal uniform tetrahedron. The cage also encapsulates an SbF₆ anion. ¹⁹F NMR spectra in solution for the analogous PF₆ complex [Ag₄(L1)₃(L2)(PF₆)]³⁺, 1-PF₆, confirm that one anion is also encapsulated in solution The synthesis of the analogous CF₃SO₃^– complex, [Ag₄(L1)₃(L2)(OTf)]³⁺, 1-OTf, in solution is also described, although 1-PF₆ and 1-OTf could not be isolated due to slow decomposition in solution The selective formation of these mixed-ligand cages is discussed in terms of ligand-ligand and ligand-included anion steric repulsions, which the authors propose prevent the formation of the competing hypothetical homoligand tetrahedral structure [Ag₄(L1)₄(SbF₆)]³⁺, and thus favor the mixed ligand cage. Cage cone angles for L1 and L2 are estimated at 115° and 101°, resp. Variable-temperature ³¹P NMR spectroscopy shows that complex 1-SbF₆ and the related previously reported partial tetrahedral complex [Ag₄(L1)₃(anion)]³⁺ undergo dynamic twisting processes in solution between enantiomeric C₃-symmetry conformations. This study involved multiple reactions and reactants, such as 2,2′,2”-(2,4,6-Trimethylbenzene-1,3,5-triyl)triacetonitrile (cas: 16144-65-3Application In Synthesis of 2,2′,2”-(2,4,6-Trimethylbenzene-1,3,5-triyl)triacetonitrile).

2,2′,2”-(2,4,6-Trimethylbenzene-1,3,5-triyl)triacetonitrile (cas: 16144-65-3) belongs to nitriles. The R-C-N bond angle in and nitrile is 180° which give a nitrile functional group a linear shape. Both the carbon and the nitrogen are sp hydridized which leaves them both with two p orbitals which overlap to form the two π bond in the triple bond. Alkyl nitriles are sufficiently acidic to undergo deprotonation of the C-H bond adjacent to the CN group.Strong bases are required, such as lithium diisopropylamide and butyl lithium. The product is referred to as a nitrile anion. Application In Synthesis of 2,2′,2”-(2,4,6-Trimethylbenzene-1,3,5-triyl)triacetonitrile

Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts