《Direct use of 1,3-dienes for the allylation of ketones via catalytic hydroindation》 was written by Suzuki, Itaru; Yagi, Kensuke; Miyamoto, Shinji; Shibata, Ikuya. Product Details of 614-16-4 And the article was included in RSC Advances in 2020. The article conveys some information:
In this study, in situ catalytically generated allylic indium from 1,3-dienes and InCl2H was developed for use in the allylation of ketones. This protocol resulted in the unprecedented establishment of a successive combining of quaternary C-C bonds, which could then be applied to many types of ketones. Other branched 1,3-dienes and vinyl cyclopropanes, could also be coupled with ketones to get homoallylic alcs. I [R1 = Ph, 4-MeC6H4, 4-ClC6H4, etc.; R2 = Me, Et, n-Pr, etc.] in a reaction where CuH would not be applicable. In the experiment, the researchers used many compounds, for example, 3-Oxo-3-phenylpropanenitrile(cas: 614-16-4Product Details of 614-16-4)
3-Oxo-3-phenylpropanenitrile(cas: 614-16-4) has been used to produce 2-benzoyl-3-furan-2-yl-acrylonitrile. It is an active methylene compound, useful in heterocyclic synthesis, e.g. polyfunctional pyridines and pyrimidines.Product Details of 614-16-4
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts