The author of 《Water elimination rate measurements for tertiary-butanol》 were Heyne, J.; Dooley, S.; Dryer, F.. And the article was published in Chemical and Physical Processes in Combustion in 2011. Product Details of 658-98-0 The author mentioned the following in the article:
Alternatives to petroleum derived transportation fuels, particularly C4 alcs. (butanols), have been investigated increasingly over the last three years. One butanol isomer, teritary-butanol (derived from petroleum), is already used com. as a gasoline octane number enhancer. Studies of tertiary-butanol (t-butanol) combustion suggest that the water elimination channel (C4H9OH = iC4H8 + H2O) can contribute to approx. 75% of t-butanol consumption in flames [1]. A study of this key reaction has recently been performed in the Princeton Variable Pressure Flow Reactor (VPFR) using radical trappers to isolate this path in t-butanol pyrolysis experiments Radical trappers consume radicals produced in the pyrolysis sufficiently fast to preclude significant secondary radical reactions with t-butanol. Numerical experiments were conducted to estimate the appropriate radical trapper (1,3,5-trimethylbenzene) to fuel (t-butanol) molar ratios. The water elimination reaction was then studied in the temperature range of 658-980 K at 6.1 atm. The rate determination of water elimination reaction of t-butanol at each temperature was found by using a global least squares fit considering the species of water and isobutene. The resulting rates are then compared to previous exptl., computational and estimated rate currently in the literature. Anal. suggests that the water elimination reaction is faster than estimated from previous exptl. studies and occurs at a rate in good agreement with some more recent rate estimations [2].3-Chloro-4-fluorophenylacetonitrile(cas: 658-98-0Product Details of 658-98-0) was used in this study.
3-Chloro-4-fluorophenylacetonitrile(cas: 658-98-0) belongs to nitriles. Nitriles are found in many useful compounds. Nitrile rubber is also widely used as automotive and other seals since it is resistant to fuels and oils. Organic compounds containing multiple nitrile groups are known as cyanocarbons.Product Details of 658-98-0
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts