Ye, Jian-Heng; Bellotti, Peter; Heusel, Corinna; Glorius, Frank published an article on February 21 ,2022. The article was titled 《Photoredox-Catalyzed Defluorinative Functionalizations of Polyfluorinated Aliphatic Amides and Esters》, and you may find the article in Angewandte Chemie, International Edition.Product Details of 1403850-00-9 The information in the text is summarized as follows:
A new catalytic approach to the selective functionalization of strong C-F bonds in polyfluorinated aliphatic esters and amides was reported. This simple reaction proceeded in mild and operational fashion with divergent conversions, including hydrodefluorination, defluoroalkylation and defluoroalkenylation, affording a diverse array of important partially fluorinated motifs. Straightforward downstream chem. towards fluorinated alcs., amines and drug derivatives highlights the potential of the protocol. The experimental process involved the reaction of 2,4,6-Tris(diphenylamino)-3,5-difluorobenzonitrile(cas: 1403850-00-9Product Details of 1403850-00-9)
2,4,6-Tris(diphenylamino)-3,5-difluorobenzonitrile(cas: 1403850-00-9) is cyanoarene-based donor-acceptor photocatalyst developed by the Zeitler group. While this catalyst has a balanced redox profile, allowing for its use in a variety of transformations, it stands out as the most reducing catalyst of the family.Product Details of 1403850-00-9
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts