Related Products of 17524-05-9. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: Bis(acetylacetonato)dioxomolybdenum(VI), is researched, Molecular C10H14MoO6, CAS is 17524-05-9, about Enhanced Photoelectrochemical Water Oxidation Performance by Fluorine Incorporation in BiVO4 and Mo:BiVO4 Thin Film Photoanodes. Author is Rohloff, Martin; Anke, Bjoern; Kasian, Olga; Zhang, Siyuan; Lerch, Martin; Scheu, Christina; Fischer, Anna.
Anion substitution is an emerging strategy to enhance the photoelectrochem. performance of metal oxide photoelectrodes. In the present work, the effect is investigated of fluorine incorporation on the photoelectrochem. water oxidation performance of BiVO4 and Mo:BiVO4 thin film photoanodes. The BiVO4 and Mo:BiVO4 thin film photoanodes were prepared by a straightforward organometallic solution route involving dip coating and subsequent calcination in air. Fluorine modification was realized by applying a soft and low-cost solid-vapor reaction route involving fluorine-containing polymers and an inert gas atm. leading to novel F:BiVO4 and F/Mo:BiVO4 thin film photoanodes with substantially increased photoelectrochem. water oxidation properties. Deposition of the cobalt phosphate (CoPi) water oxidation catalyst allowed further enhancement of the photoelectrochem. performance. While Mo doping mainly improves light-harvesting, charge transport, and charge separation efficiencies, F modification was demonstrated to primarily affect the charge transfer efficiency at the semiconductor-electrolyte interface, thereby leading to a photocurrent increase of 40 and 21% upon fluorination of the BiVO4 and Mo:BiVO4 photoanodes, resp., and an applied bias photon-to-current efficiency increase of 35 and 5%, resp. It is demonstrated that cation and anion co-doping in BiVO4 as demonstrated for Mo and F allows combining the photoelectrochem. relevant benefits associated with each type of dopant.
This compound(Bis(acetylacetonato)dioxomolybdenum(VI))Related Products of 17524-05-9 was discussed at the molecular level, the effects of temperature and reaction time on the properties of the compound were discussed, and the optimum reaction conditions were selected.
Reference:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts