Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 17524-05-9, is researched, SMILESS is O=[Mo+2]12(O=C([CH-]C(C)=O1)C)(O=C([CH-]C(C)=O2)C)=O, Molecular C10H14MoO6Journal, Polyhedron called DMSO coordinated dioxidomolybdenum(VI) complexes chelated with 3-methoxybenzhydrazone related ligands: Synthesis, structural studies and in vitro cytotoxicity, Author is Asha, T. M.; Kurup, M. R. P., the main research direction is molybdenum oxido methoxybenzhydrazone complex preparation cytotoxicity electrochem thermal stability; Hirshfeld surface molybdenum oxido methoxybenzhydrazone complex; crystal structure molybdenum oxido methoxybenzhydrazone complex.HPLC of Formula: 17524-05-9.
Three new DMSO coordinated dioxidomolybdenum(VI) complexes [MoO2L3OMe(DMSO)] (1), [MoO2L4OMe(DMSO)] (2) and [MoO2L5OMe(DMSO)] (3) (where, L3OMe = 2-oxy-3-methoxybenzaldehyde-3-methoxy-benzhydrazonato, L4OMe = 2-oxy-4-methoxybenzaldehyde-3-methoxybenzhydrazonato and L5OMe = 2-oxy-5-methoxybenzaldehyde-3-methoxybenzhydrazonato) (Scheme 1) were synthesized by reacting [MoO2(acac)2] with the corresponding aroylhydrazone in presence of the solvent, DMSO and fully characterized. The various characterization techniques included elemental anal., spectroscopic techniques (IR, electronic and 1H NMR), thermogravimetric anal. and cyclic voltammetry. The mol. and crystal structures of 1, 2 and 3 were determined by single crystal X-ray diffraction method. In all complexes, the molybdenum atom displays a distorted octahedral geometry. In addition, the discussion on coordination geometries and non-covalent interactions were also supported using Hirshfeld surface anal. The in vitro cytotoxicity of the aroylhydrazone ligands and their molybdenum complexes against lymphoma ascites cell line demonstrated that the complexes are more cytotoxic than their corresponding ligands.
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Reference:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts