Reference of tert-Butyl (2-(bromomethyl)phenyl)carbamate. Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: tert-Butyl (2-(bromomethyl)phenyl)carbamate, is researched, Molecular C12H16BrNO2, CAS is 166329-43-7, about Photoredox-Catalyzed Trifluoromethylative Intramolecular Cyclization: Synthesis of CF3-Containing Heterocyclic Compounds. Author is Han, Hong Sik; Oh, Eun Hye; Jung, Young-Sik; Han, Soo Bong.
In the presence of Ir(ppy)3 and under blue LED irradiation, arylalkynyl alcs. and protected amines and an alkynyl thiol underwent chemoselective and regioselective trifluoromethylation and cyclization reactions mediated by Li2CO3 in dry MeCN to yield trifluoromethylated cyclic enol ethers and amines and a dihydrothiopyran such as I (R = 4-MeCONHC6H4, 4-TsNHC6H4, 4-BocNHC6H4, Ph, 4-t-BuC6H4, 4-MeOC6H4, 4-ClC6H4, 4-BrC6H4; R1 = H, Me; X = O, TsN, S; Ts = 4-MeC6H4SO2; Boc = t-BuOCO) in 41-80% yields. Seven- and eight-membered cyclic enol ethers were also prepared using this method.
In some applications, this compound(166329-43-7)Reference of tert-Butyl (2-(bromomethyl)phenyl)carbamate is unique.If you want to know more details about this compound, you can contact with the author or consult more relevant literature.
Reference:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts