Electrochemical reduction of pristinamycin IA and related streptogramins in aqueous acidic medium was written by Largeron, M.;Vuilhorgne, M.;Le Potier, I.;Auziel, N.;Bacque, E.;Paris, J. M.;Fleury, M. B.. And the article was included in Tetrahedron in 1994.Recommanded Product: 10282-32-3 This article mentions the following:
The electrochem. reduction of the picolinoyl residue of pristinamycin IA and related streptogramins was performed at a mercury cathode, in aqueous acidic medium. The presence of a peptidic lactone residue at the amide nitrogen atom markedly modified the expected cathodic behavior of pyridyl carboxamides: in particular, the pyridyl ring was reduced to tetrahydropyridine. Thanks to a series of model heterocyclic carboxamides, increasing steric hindrance at the amide nitrogen position was shown to lead to enhanced reduction of the heterocyclic ring. In the experiment, the researchers used many compounds, for example, 4-(Benzylamino)benzonitrile (cas: 10282-32-3Recommanded Product: 10282-32-3).
4-(Benzylamino)benzonitrile (cas: 10282-32-3) belongs to nitriles. Nitriles are polar, as indicated by high dipole moments. As liquids, they have high relative permittivities, often in the 30s. Nitriles are susceptible to hydrogenation over diverse metal catalysts. The reaction can afford either the primary amine (RCH2NH2) or the tertiary amine ((RCH2)3N), depending on conditions.Recommanded Product: 10282-32-3
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts