Jensen, Rader S. published the artcileSynthesis and catalytic properties of cationic palladium(II) and rhodium(I) complexes bearing diphosphinidinecyclobutene ligands, Application of Tetrakis(acetonitrile)palladium(II) Ditriflate, the publication is Journal of Organometallic Chemistry (2007), 692(1-3), 286-294, database is CAplus.
Cationic Pd(II) and Rh(I) complexes bearing 1,2-diaryl-3,4-bis[(2,4,6-tri-t-butylphenyl)phosphinidene]cyclobutene ligands (DPCB-Y) were prepared and their structures and catalytic activity were examined (aryl = Ph (DPCB), 4-methoxyphenyl (DPCB-OMe), 4-(trifluoromethyl)phenyl (DPCB-CF3)). The Pd complexes [Pd(MeCN)2(DPCB-Y)]X2 (X = OTf, BF4, BAr4 (Ar = 3,5-bis(trifluoromethyl)phenyl)) were prepared by the reactions of DPCB-Y with [Pd(MeCN)4]X2, which were generated from Pd(OAc)2 and HX in MeCN. However, the Rh complexes [Rh(MeCN)2(DPCB-Y)]OTf were prepared by the treatment of [Rh(μ-Cl)(cyclooctadiene)2]2 with DPCB-Y in CH2Cl2, followed by treatment with AgOTf in the presence of MeCN. The cationic complexes catalyzed conjugate addition of benzyl carbamate to α,β-unsaturated ketones.
Journal of Organometallic Chemistry published new progress about 68569-14-2. 68569-14-2 belongs to nitriles-buliding-blocks, auxiliary class Palladium, name is Tetrakis(acetonitrile)palladium(II) Ditriflate, and the molecular formula is C10H12F6N4O6PdS2, Application of Tetrakis(acetonitrile)palladium(II) Ditriflate.
Referemce:
https://en.wikipedia.org/wiki/Nitrile,
Nitriles – Chemistry LibreTexts