Kita, Yusuke published the artcileRhodium-catalyzed carbon-cyano bond cleavage reactions using organosilicon reagents, SDS of cas: 214360-44-8, the publication is Yuki Gosei Kagaku Kyokaishi (2010), 68(11), 1112-1122, database is CAplus.
Rh-catalyzed C-cyano bond cleavage reactions using organosilicon reagents are described. When disilane is used as the Si reagent, the C-CN bonds in aryl and alkenyl cyanides are silylated to form the corresponding silylated products along with silyl cyanide. Reductive decyanation of nitriles is achieved when hydrosilane is used as the Si reagent. This catalytic system can be applied to the C(sp3)-CN bonds in simple aliphatic nitriles. In both reactions, the silylrhodium species generated in situ serves as a catalytically active species, cleaving C-CN bonds via an η2-iminoacyl complex. Addition of external electrophiles allowed the Si-assisted cleavage of C-CN bonds to be applied to C-C bond formation reactions. Intramol. arylation of benzonitrile bearing a tethered chlorophenyl group and decyanative Mizoroki-Heck-type alkenylation of nitriles with vinylsilanes have been developed.
Yuki Gosei Kagaku Kyokaishi published new progress about 214360-44-8. 214360-44-8 belongs to nitriles-buliding-blocks, auxiliary class Nitrile,Boronic acid and ester,Benzene,Boronic Acids,Boronic acid and ester, name is 4-(5,5-Dimethyl-1,3,2-dioxaborinan-2-yl)benzonitrile, and the molecular formula is C12H14BNO2, SDS of cas: 214360-44-8.
Referemce:
https://en.wikipedia.org/wiki/Nitrile,
Nitriles – Chemistry LibreTexts