Diosdado, Saioa’s team published research in Angewandte Chemie, International Edition in 52 | CAS: 5153-73-1

Angewandte Chemie, International Edition published new progress about 5153-73-1. 5153-73-1 belongs to nitriles-buliding-blocks, auxiliary class Nitrile,Alkenyl,Nitro Compound,Benzene, name is (E)-4-(2-Nitrovinyl)benzonitrile, and the molecular formula is C9H6N2O2, Computed Properties of 5153-73-1.

Diosdado, Saioa published the artcileCatalytic Enantioselective Synthesis of Tertiary Thiols From 5H-Thiazol-4-ones and Nitroolefins: Bifunctional Ureidopeptide-Based Bronsted Base Catalysis, Computed Properties of 5153-73-1, the publication is Angewandte Chemie, International Edition (2013), 52(45), 11846-11851, database is CAplus and MEDLINE.

The synthesis of the target compounds was achieved using urea-peptide analogs as catalysts (Bronsted acids). A reaction of amino acids (L-valine, 3-methyl-L-valine) with (8α,9S)-6′-methoxycinchonan-9-amine (epiquinine, cinchona alkaloid derivative) provided the above-mentioned urea-peptide analogs. These catalysts were applied in a Michael reaction of thiazolone derivatives with (nitro)alkenes. A reaction of 2-mercaptobutanoic acid, 2-(mercapto)octanoic acid, α-(mercapto)benzenepropanoic acid with nitriles provided 4-thiazolol derivatives (4-thiazolone derivatives). The title compounds thus formed included a thiazolone nitroalkane derivative (I) and related substances, quinoline derivatives, naphthalene derivatives, etc.

Angewandte Chemie, International Edition published new progress about 5153-73-1. 5153-73-1 belongs to nitriles-buliding-blocks, auxiliary class Nitrile,Alkenyl,Nitro Compound,Benzene, name is (E)-4-(2-Nitrovinyl)benzonitrile, and the molecular formula is C9H6N2O2, Computed Properties of 5153-73-1.

Referemce:
https://en.wikipedia.org/wiki/Nitrile,
Nitriles – Chemistry LibreTexts