Pearson, David M. published the artcileOxidatively Resistant Ligands for Palladium-Catalyzed Aerobic Alcohol Oxidation, Recommanded Product: Tetrakis(acetonitrile)palladium(II) Ditriflate, the publication is Organometallics (2011), 30(6), 1445-1453, database is CAplus.
[(Neocuproine)Pd(OAc)]2[OTf]2 (1) catalyzes the aerobic oxidation of 2-heptanol at room temperature, but competitive ligand oxidation leads to low catalyst lifetimes. In an effort to mitigate the oxidative degradation of the ligand, a variety of Pd complexes ligated by fluorinated phenanthrolines (bis-2,9-(trifluoromethyl)-1,10-phenanthroline (btfm-phen), 4-methyl-2-(trifluoromethyl)-1,10-phenanthroline (tfmm-phen), and 2-(o-difluorophenyl)-1,10-phenanthroline (odfp-phen)) were prepared and tested. Active catalyst precursors were generated by in situ conproportionation of (N-N)Pd(OAc)2 and [(N-N)Pd(NCCH3)2[OTf]2]. Pd complexes derived from tfmm-phen catalyzed the aerobic oxidation of 2-heptanol at room temperature with up to 22 turnovers, nearly double that of 1.
Organometallics published new progress about 68569-14-2. 68569-14-2 belongs to nitriles-buliding-blocks, auxiliary class Palladium, name is Tetrakis(acetonitrile)palladium(II) Ditriflate, and the molecular formula is C10H12F6N4O6PdS2, Recommanded Product: Tetrakis(acetonitrile)palladium(II) Ditriflate.
Referemce:
https://en.wikipedia.org/wiki/Nitrile,
Nitriles – Chemistry LibreTexts