Huang, Zijun’s team published research in Chemical Communications (Cambridge, United Kingdom) in 54 | CAS: 68569-14-2

Chemical Communications (Cambridge, United Kingdom) published new progress about 68569-14-2. 68569-14-2 belongs to nitriles-buliding-blocks, auxiliary class Palladium, name is Tetrakis(acetonitrile)palladium(II) Ditriflate, and the molecular formula is C10H12F6N4O6PdS2, Recommanded Product: Tetrakis(acetonitrile)palladium(II) Ditriflate.

Huang, Zijun published the artcileRegioselectivity inversion tuned by iron(III) salts in palladium-catalyzed carbonylations, Recommanded Product: Tetrakis(acetonitrile)palladium(II) Ditriflate, the publication is Chemical Communications (Cambridge, United Kingdom) (2018), 54(32), 3967-3970, database is CAplus and MEDLINE.

By using cheap and abundant iron(III) salts, the hydroxycarbonylations of both aromatic and aliphatic alkenes were significantly enhanced in both reactivity and selectivity (iso/n or n/iso up to >99 : 1). Moreover, Pd-catalyzed carbonylation selectivity can be switched from branched to linear by using different Fe(III) salts. In addition, similar results were obtained for the carbonylation of secondary alcs.

Chemical Communications (Cambridge, United Kingdom) published new progress about 68569-14-2. 68569-14-2 belongs to nitriles-buliding-blocks, auxiliary class Palladium, name is Tetrakis(acetonitrile)palladium(II) Ditriflate, and the molecular formula is C10H12F6N4O6PdS2, Recommanded Product: Tetrakis(acetonitrile)palladium(II) Ditriflate.

Referemce:
https://en.wikipedia.org/wiki/Nitrile,
Nitriles – Chemistry LibreTexts