Vijeta, Arjun published the artcileAn Integrated Carbon Nitride-Nickel Photocatalyst for the Amination of Aryl Halides Using Sodium Azide, Computed Properties of 1885-29-6, the main research area is primary aniline preparation; haloarene sodium azide amination integrated carbon nitride nickel photocatalyst; Carbon Nitride; Green Chemistry; Heterogeneous Catalysis; Organic Synthesis; Photocatalysis.
A photocatalytic protocol for the selective synthesis of primary anilines RNH2 [R = Ph, 4-BrC6H4, 3-pyridyl, etc.] via cross-coupling of a wide range of aryl/heteroaryl halides with sodium azide using a photocatalyst powder consisting of nickel(II) deposited on mesoporous carbon nitride (Ni-mpg-CNx) was reported. This heterogeneous photocatalyst contained a high surface area with a visible light-absorbing and adaptive “”built-in”” solid-state ligand for the integrated catalytic Ni site. The method displayed a high functional group tolerance, required mild reaction conditions, and benefited from easy recovery and reuse of the photocatalyst powder. Thereby, it overcame the need of complex ligand scaffolds required in homogeneous catalysis, precious metals and elevated temperatures/pressures in existing protocols of primary anilines synthesis. The reported heterogeneous Ni-mpg-CNx held potential for applications in the academic and industrial synthesis of anilines and exploration of other photocatalytic transformations.
Angewandte Chemie, International Edition published new progress about Amination. 1885-29-6 belongs to class nitriles-buliding-blocks, name is 2-Aminobenzonitrile(Flakes or Chunks), and the molecular formula is C7H6N2, Computed Properties of 1885-29-6.
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts