Electrochemical oxidation of organic compounds in fluorosulfuric acid. IV. Voltammetric study of the formation and of the anodic behavior of some benzyl cations and arenium ions was written by Rudenko, A. P.;Zarubin, M. Ya.;Pragst, F.. And the article was included in Journal fuer Praktische Chemie (Leipzig) in 1983.Related Products of 16144-65-3 The following contents are mentioned in the article:
A cyclic voltammetric study of the oxidation of benzylic alcs., ethers, acetates, and cyanides and of aromatic hydrocarbons in FSO3H at -76° was reported. Benzyl cations were oxidized at potentials 0.7-0.8 V more pos. than those of the neutral compounds to [ArCH2OSO2F]+• cation radicals. In a subsequent step another Me group was functionalized to CH2OSO2F. The anodic peak potentials of the arenium ions was ∼1.1 V more pos. than those of the nonprotonated hydrocarbons. The dissociation equilibrium of ArCH2OSO2F and the protonation equilibrium of the hydrocarbons were discussed in terms of the donor ability of the aromatic compounds in borderline cases. This study involved multiple reactions and reactants, such as 2,2′,2”-(2,4,6-Trimethylbenzene-1,3,5-triyl)triacetonitrile (cas: 16144-65-3Related Products of 16144-65-3).
2,2′,2”-(2,4,6-Trimethylbenzene-1,3,5-triyl)triacetonitrile (cas: 16144-65-3) belongs to nitriles. Nitrile compounds can be prepared by the incorporation of a cyanide source through C–C bond formation or by dehydration of primary carboxamides. In conventional organic reductions, nitrile is reduced by treatment with lithium aluminium hydride to the amine. Reduction to the imine followed by hydrolysis to the aldehyde takes place in the Stephen aldehyde synthesis, which uses stannous chloride in acid.Related Products of 16144-65-3
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts