Dynamic modeling of consecutive reactions: application to the acrylonitrile amination was written by Kadri, Brahim;Fabre, Bernard;Accary, Armand;Kessler, Mathieu. And the article was included in Canadian Journal of Chemical Engineering in 1998.Quality Control of 3,3′,3”-Nitrilotripropanenitrile This article mentions the following:
When dealing with optimal control problems to maximize the selectivity of reactions for fine chem. synthesis, representative kinetic and thermodn. models should be available. While literature appears to be very extensive on theor. approaches to solve the problem, examples presenting complete models of chem. transformations are scarce. This paper presents the identification of consecutive reactions carried out in a batch reactor. Material and energy balances, satisfying dynamical state evolutions in the temperature range 20-60°C are deduced, for concentrations of acrylonitrile ranging up to 1.6 kmol·m-3. The stoichiometric network is simplified into two reactions, one reversible and one irreversible. Reaction enthalpies are measured from isothermal runs conducted in the RC1 heat-flow calorimeter from Mettler Toledo. In the experiment, the researchers used many compounds, for example, 3,3′,3”-Nitrilotripropanenitrile (cas: 7528-78-1Quality Control of 3,3′,3”-Nitrilotripropanenitrile).
3,3′,3”-Nitrilotripropanenitrile (cas: 7528-78-1) belongs to nitriles. The electronic structure of nitriles is very similar to that of an alkyne with the main difference being the presence of a set of lone pair electrons on the nitrogen. Industrially, the main methods for producing nitriles are ammoxidation and hydrocyanation. Both routes are green in the sense that they do not generate stoichiometric amounts of salts.Quality Control of 3,3′,3”-Nitrilotripropanenitrile
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts