Sotnik, Svetlana A. et al. published their research in Inorganic Chemistry in 2015 | CAS: 55490-87-4

2-(Anthracen-9-ylmethylene)malononitrile (cas: 55490-87-4) belongs to nitriles. Nitrile function is a very important functional group because it can be manipulated to other functional groups such as carboxylic acid by hydrolysis or amine by reduction, respectively. Some nitriles are manufactured by heating carboxylic acids with ammonia in the presence of catalysts. This process is used to make nitriles from natural fats and oils, the products being used as softening agents in synthetic rubbers, plastics, and textiles and for making amines.Recommanded Product: 55490-87-4

Heterometallic Coordination Polymers Assembled from Trigonal Trinuclear Fe2Ni-Pivalate Blocks and Polypyridine Spacers: Topological Diversity, Sorption, and Catalytic Properties was written by Sotnik, Svetlana A.;Polunin, Ruslan A.;Kiskin, Mikhail A.;Kirillov, Alexander M.;Dorofeeva, Victoria N.;Gavrilenko, Konstantin S.;Eremenko, Igor L.;Novotortsev, Vladimir M.;Kolotilov, Sergey V.. And the article was included in Inorganic Chemistry in 2015.Recommanded Product: 55490-87-4 This article mentions the following:

Linkage of the trigonal complex [Fe2NiO(Piv)6] (Piv– = pivalate) by polypyridine ligands, namely, tris(4-pyridyl)triazine (L2), 2,6-bis(3-pyridyl)-4-(4-pyridyl)pyridine (L3), N-(bis-2,2-(4-pyridyloxymethyl)-3-(4-pyridyloxy)propyl)pyridone-4 (L4), and 4-(N,N-diethylamino)phenyl-bis-2,6-(4-pyridyl)pyridine (L5) gave novel coordination polymers [Fe2NiO(Piv)6(L2)]n (2), [Fe2NiO(Piv)6(L3)]n (3), [Fe2NiO(Piv)6(L4)]n·nHPiv (4), and [{Fe2NiO(Piv)6}4{L5}6]n·3nDEF (5, where DEF is N,N-diethylformamide), which were crystallog. characterized. The topol. anal. of 3, 4, and 5 disclosed the 3,3,4,4-connected 2-dimensional (3, 4) or 3,4,4-connected 1-dimensional (5) underlying networks which, upon further simplification, gave rise to the uninodal 3-connected nets with the resp. fes (3, 4) or SP 1-periodic net (4,4)(0,2) (5) topologies, driven by the cluster [Fe2Ni(μ3-O)(μ-Piv)6] nodes and the polypyridine μ3-L3,4 or μ2-L5 blocks. The obtained topologies were compared with those identified in other closely related derivatives [Fe2NiO(Piv)6(L1)]n (1) and {Fe2NiO(Piv)6}8{L6}12 (6), where L1 and L6 are tris(4-pyridyl)pyridine and 4-(N,N-dimethylamino)phenyl-bis-2,6-(4-pyridyl)pyridine, resp. A key structure-driven role in defining the dimensionality and topol. of the resulting coordination network is played by the type of polypyridine spacer. Compounds 2 and 3 possess a porous structure, as confirmed by the N2 and H2 sorption data at 78 K. Methanol and ethanol sorption by 2 was also studied indicating that the pores filled by these substrates did not induce any structural rearrangement of this sorbent. Addnl., porous coordination polymer 2 was also applied as a heterogeneous catalyst for the condensation of salicylaldehyde or 9-anthracenecarbaldehyde with malononitrile. The best activity of 2 was observed in the case of salicylaldehyde substrate, resulting in up to 88% conversion into 2-imino-2H-chromen-3-carbonitrile. In the experiment, the researchers used many compounds, for example, 2-(Anthracen-9-ylmethylene)malononitrile (cas: 55490-87-4Recommanded Product: 55490-87-4).

2-(Anthracen-9-ylmethylene)malononitrile (cas: 55490-87-4) belongs to nitriles. Nitrile function is a very important functional group because it can be manipulated to other functional groups such as carboxylic acid by hydrolysis or amine by reduction, respectively. Some nitriles are manufactured by heating carboxylic acids with ammonia in the presence of catalysts. This process is used to make nitriles from natural fats and oils, the products being used as softening agents in synthetic rubbers, plastics, and textiles and for making amines.Recommanded Product: 55490-87-4

Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts