Remarkably stable (Me3Al)2·DABCO and stereoselective nickel-catalyzed AlR3 (R = Me, Et) additions to aldehydes was written by Biswas, Kallolmay;Prieto, Oscar;Goldsmith, Paul J.;Woodward, Simon. And the article was included in Angewandte Chemie, International Edition in 2005.Computed Properties of C9H9NO This article mentions the following:
Chiral nonracemic secondary alcs. are prepared by the addition of either bis(trialkylaluminum) adducts of DABCO or trialkylaluminum reagents to aldehydes in the presence of Ni(acac)2 and the Feringa binaphthyl phosphoramidite ligand derived from (R)-BINOL and (S,S)-N,N-bis(1-phenylethyl)amine. In the experiment, the researchers used many compounds, for example, (R)-4-(1-Hydroxyethyl)benzonitrile (cas: 101219-69-6Computed Properties of C9H9NO).
(R)-4-(1-Hydroxyethyl)benzonitrile (cas: 101219-69-6) belongs to nitriles. Trimerization of aromatic nitriles requires harsh reaction conditions, high temperatures, long reaction times, and pressure. Industrially, the main methods for producing nitriles are ammoxidation and hydrocyanation. Both routes are green in the sense that they do not generate stoichiometric amounts of salts.Computed Properties of C9H9NO
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts