Sau, Abhijit published the artcilePalladium-Catalyzed Direct Stereoselective Synthesis of Deoxyglycosides from Glycals, HPLC of Formula: 68569-14-2, the publication is Angewandte Chemie, International Edition (2017), 56(13), 3640-3644, database is CAplus and MEDLINE.
Palladium(II) in combination with a monodentate phosphine ligand enables the unprecedented direct and α-stereoselective catalytic synthesis of deoxyglycosides from glycals. Initial mechanistic studies suggest that in the presence of N-phenyl-2-(di-tert-butylphosphino)pyrrole as the ligand, the reaction proceeds via an alkoxy palladium intermediate that increases the proton acidity and oxygen nucleophilicity of the alc. The method is demonstrated with a wide range of glycal donors and acceptors, including substrates bearing alkene functionalities.
Angewandte Chemie, International Edition published new progress about 68569-14-2. 68569-14-2 belongs to nitriles-buliding-blocks, auxiliary class Palladium, name is Tetrakis(acetonitrile)palladium(II) Ditriflate, and the molecular formula is C10H12F6N4O6PdS2, HPLC of Formula: 68569-14-2.
Referemce:
https://en.wikipedia.org/wiki/Nitrile,
Nitriles – Chemistry LibreTexts