Pang, Maofu published the artcileAddition of a B-H Bond across an Amido-Cobalt Bond: CoII-H-Catalyzed Hydroboration of Olefins, Product Details of C10H18BNO2, the publication is Organometallics (2018), 37(9), 1462-1467, database is CAplus.
This paper describes a well-defined cobalt(II) half-sandwich complex bearing a phosphinoaminato ligand, Cp*Co(1,2-Ph2PC6H4NH) (1), that can activate pinacolborane (HBpin) for catalytic terminal hydroboration of olefins. The cooperative cobalt(II)-amido reactivity in 1 enables the B-H bond cleavage, affording the 17-electron cobalt(II) hydride Cp*Co(1,2-Ph2PC6H4NH(Bpin)), abbreviated H1(Bpin), in which the borenium ion is captured by the uncoordinated nitrogen atom of the phosphinoaminato ligand. Hydroboration of the C:C bond can be promoted by a heteroatom such as N or O at the β-position of terminal alkenes. The mechanism of such hydroboration was established by various stoichiometric reactions based on the cobalt(II) hydride. With cooperative CoII-N reactivity for the B-H bond cleavage, our catalysis depends on the CoII-H hydride generated by the system itself.
Organometallics published new progress about 238088-16-9. 238088-16-9 belongs to nitriles-buliding-blocks, auxiliary class Nitrile,Boronic acid and ester,Aliphatic cyclic hydrocarbon,Boronic Acids,Boronate Esters, name is 4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)butanenitrile, and the molecular formula is C10H18BNO2, Product Details of C10H18BNO2.
Referemce:
https://en.wikipedia.org/wiki/Nitrile,
Nitriles – Chemistry LibreTexts