Li, Ming published the artcileCooperative Strategy for the Highly Selective Intermolecular Oxycarbonylation Reaction of Alkenes using Palladium Catalyst, Category: nitriles-buliding-blocks, the publication is Angewandte Chemie, International Edition (2016), 55(44), 13843-13848, database is CAplus and MEDLINE.
A novel method for intermol. functionalization of terminal and internal alkenes has been designed. The electrophilic reagent, hypervalent iodine, plays a key role in this process by activating the alkene C=C bond for nucleophilic addition of the palladium catalyst. This process generates an iodonium-containing palladium species which undergoes CO insertion. The new approach, intermol. oxycarbonylaton reactions of alkenes, has been achieved and carried out under mild reaction conditions to produce the corresponding β-oxycarboxylic acids with excellent efficiencies and levels of regio- and diastereoselectivity. Thus, e.g., treatment of 5-phthalimido-1-pentene with Pd(OAc)2, PhI(OAc)2, BF3.Et2O and CO in toluene/MeCN afforded I (95%, regioselectivity > 20:1).
Angewandte Chemie, International Edition published new progress about 68569-14-2. 68569-14-2 belongs to nitriles-buliding-blocks, auxiliary class Palladium, name is Tetrakis(acetonitrile)palladium(II) Ditriflate, and the molecular formula is C10H12F6N4O6PdS2, Category: nitriles-buliding-blocks.
Referemce:
https://en.wikipedia.org/wiki/Nitrile,
Nitriles – Chemistry LibreTexts