Kanega, Ryoichi published the artcileDiphenyl Carbonate Synthesis by Homogeneous Pd Electrocatalyst, Recommanded Product: Tetrakis(acetonitrile)palladium(II) Ditriflate, the publication is Topics in Catalysis (2014), 57(10-13), 995-999, database is CAplus.
Electrochem. carbonylation of phenol with CO to di-Ph carbonate (DPC) using Pd electrocatalyst was studied at P(CO) = 1 atm and room temperature Electrochem. carbonylation was conducted by galvanostatic electrolysis at 1 mA in electrolyte solutions containing phenol, Na phenoxide and MeCN. Electrochem. carbonylation by Pd was promoted by using 1,3-dimesitylimidazol-2-ylidene (IMes) ligand of a N-heterocyclic carbene. The current efficiency of DPC increased >3.4 times using the IMes ligand. The maximum current efficiency of DPC formation was 45%.
Topics in Catalysis published new progress about 68569-14-2. 68569-14-2 belongs to nitriles-buliding-blocks, auxiliary class Palladium, name is Tetrakis(acetonitrile)palladium(II) Ditriflate, and the molecular formula is C10H12F6N4O6PdS2, Recommanded Product: Tetrakis(acetonitrile)palladium(II) Ditriflate.
Referemce:
https://en.wikipedia.org/wiki/Nitrile,
Nitriles – Chemistry LibreTexts