Hao, Feiyue published the artcileDirect dihalo-alkoxylation of nitroalkenes leading to β,β-dihalo-β-nitroethyl alkyl ethers, Recommanded Product: (E)-4-(2-Nitrovinyl)benzonitrile, the publication is Organic & Biomolecular Chemistry (2018), 16(15), 2768-2775, database is CAplus and MEDLINE.
A highly efficient one-pot synthesis of β,β-dihalo-β-nitroethyl alkyl ethers such as I [R = Ph, 4-MeOC6H4, 2-naphthyl, etc.; R1 = Me, n-Pr, F3CH2C, etc.; R2 = H, F, Cl, Br, I; R3 = H, Cl, Br] was achieved by the treatment of nitroalkenes with alcs. and N-halosuccinimides in the presence of sodium hydride. The notable advantages of this protocol were mainly the involvement of simple exptl. manipulations and tolerance of a wide range of functional groups. Further transformations of the obtained ethers I, such as allylation and conversion to β,β-dihalogenated vinyl ethers, were also investigated.
Organic & Biomolecular Chemistry published new progress about 5153-73-1. 5153-73-1 belongs to nitriles-buliding-blocks, auxiliary class Nitrile,Alkenyl,Nitro Compound,Benzene, name is (E)-4-(2-Nitrovinyl)benzonitrile, and the molecular formula is C9H6N2O2, Recommanded Product: (E)-4-(2-Nitrovinyl)benzonitrile.
Referemce:
https://en.wikipedia.org/wiki/Nitrile,
Nitriles – Chemistry LibreTexts