Lubov, Dmitry P. published the artcilePalladium aminopyridine complexes catalyzed selective benzylic C-H oxidations with peracetic acid, Category: nitriles-buliding-blocks, the publication is Dalton Transactions (2020), 49(32), 11150-11156, database is CAplus and MEDLINE.
Four palladium(II) complexes with tripodal ligands of the tpa family (tpa = tris(2-pyridylmethyl)amine) was synthesized and X-ray characterized. These complexes efficiently catalyzed benzylic C-H oxidation of various substrates with peracetic acid, affording the corresponding ketones in high yields (up to 100%), at < 1 mol% catalyst loadings. Complex [(tpa)Pd(OAc)](PF6) with the least sterically demanding ligand tpa demonstrated the highest substrate conversions and ketone selectivities. Preliminary mechanistic data provided evidence in favor of metal complex-mediated rate-limiting benzylic C-H bond cleavage by an electron-deficient oxidant.
Dalton Transactions published new progress about 68569-14-2. 68569-14-2 belongs to nitriles-buliding-blocks, auxiliary class Palladium, name is Tetrakis(acetonitrile)palladium(II) Ditriflate, and the molecular formula is C10H12F6N4O6PdS2, Category: nitriles-buliding-blocks.
Referemce:
https://en.wikipedia.org/wiki/Nitrile,
Nitriles – Chemistry LibreTexts