Kwiatkowski, Jacek published the artcileHighly Enantioselective Michael Addition of 2-Fluoro-1,3-diketones to Nitroalkenes, Formula: C9H6N2O2, the publication is European Journal of Organic Chemistry (2015), 2015(2), 320-324, database is CAplus.
The highly enantioselective Michael addition of 2-fluoro-1,3-diketones R1C(O)CHFC(O)R2 (R1 = Ph, phenanthren-3-yl, furan-2-yl, 4-BrC6H4; R2 = Me, i-Pr) to nitroalkenes R3CH:CHNO2 (R3 = i-Pr, Ph, 2-FC6H4, etc.) was developed, and the desired adducts I were obtained in good chem. yields with good diastereoselectivities and excellent enantioselectivities. Subsequent stereoselective reduction of the carbonyl groups led to the preparation of a functionalized fluoro isostere of glycerol that contains four continuous stereogenic centers.
European Journal of Organic Chemistry published new progress about 5153-73-1. 5153-73-1 belongs to nitriles-buliding-blocks, auxiliary class Nitrile,Alkenyl,Nitro Compound,Benzene, name is (E)-4-(2-Nitrovinyl)benzonitrile, and the molecular formula is C9H6N2O2, Formula: C9H6N2O2.
Referemce:
https://en.wikipedia.org/wiki/Nitrile,
Nitriles – Chemistry LibreTexts