August, David P. published the artcileMaximizing Coordination Capsule-Guest Polar Interactions in Apolar Solvents Reveals Significant Binding, Formula: C10H12F6N4O6PdS2, the publication is Angewandte Chemie, International Edition (2016), 55(48), 15022-15026, database is CAplus and MEDLINE.
Guest encapsulation underpins the functional properties of self-assembled capsules yet identifying systems capable of strongly binding small organic mols. in solution remains a challenge. Most coordination capsules rely on the hydrophobic effect to ensure effective solution-phase association In contrast, we show that using non-interacting anions in apolar solvents can maximize favorable interactions between a cationic Pd2L4 host and charge-neutral guests resulting in a dramatic increase in binding strength. With quinone-type guests, association constants in excess of 108 M-1 were observed, comparable to the highest previously recorded constant for a metallosupramol. capsule. Modulation of optoelectronic properties of the guests was also observed, with encapsulation either changing or switching-on luminescence not present in the bulk phase.
Angewandte Chemie, International Edition published new progress about 68569-14-2. 68569-14-2 belongs to nitriles-buliding-blocks, auxiliary class Palladium, name is Tetrakis(acetonitrile)palladium(II) Ditriflate, and the molecular formula is C10H12F6N4O6PdS2, Formula: C10H12F6N4O6PdS2.
Referemce:
https://en.wikipedia.org/wiki/Nitrile,
Nitriles – Chemistry LibreTexts