Zhang, Jin-Jiang published the artcileTransition-metal free C-C bond cleavage/borylation of cycloketone oxime esters, HPLC of Formula: 238088-16-9, the publication is Chemical Science (2019), 10(1), 161-166, database is CAplus and MEDLINE.
An efficient transition-metal free C-C bond cleavage/borylation of cycloketone oxime esters has been described. In this reaction, the tetrahydroxydiborane (B2(OH)4) reagent not only served as the boron source but also acted as an electron donor source through formation of a complex with a N,N-dimethylacetamide (DMAc)-like Lewis base. This complex could be used as an efficient single electron reductant in other ring-opening transformations of cycloketone oxime esters. Free-radical trapping, radical-clock, and DFT calculations all suggest a radical pathway for this transformation.
Chemical Science published new progress about 238088-16-9. 238088-16-9 belongs to nitriles-buliding-blocks, auxiliary class Nitrile,Boronic acid and ester,Aliphatic cyclic hydrocarbon,Boronic Acids,Boronate Esters, name is 4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)butanenitrile, and the molecular formula is C9H9BrO2, HPLC of Formula: 238088-16-9.
Referemce:
https://en.wikipedia.org/wiki/Nitrile,
Nitriles – Chemistry LibreTexts