Liu, Bei-Bei published the artcileAqueous Reaction of Alcohols, Organohalides, and Odorless Sodium Thiosulfate under Transition-Metal-Free Conditions: Synthesis of Unsymmetrical Aryl Sulfides via Dual C-S Bond Formation, Synthetic Route of 612-13-5, the publication is Journal of Organic Chemistry (2017), 82(19), 10174-10180, database is CAplus and MEDLINE.
A transition-metal-free process for the synthesis of unsym. aryl sulfides via dual C-S bond formation by a one-pot three-component reaction of alcs., organohalides, and odorless sodium thiosulfate in water was developed. In addition, the aryl sulfides could also be prepared by the reaction of the corresponding alcs. and Bunte salts under the identical conditions. This protocol provides a green and efficient manner for the construction of various unsym. aryl sulfides.
Journal of Organic Chemistry published new progress about 612-13-5. 612-13-5 belongs to nitriles-buliding-blocks, auxiliary class Organic Pigment, name is 2-(Chloromethyl)benzonitrile, and the molecular formula is C8H6ClN, Synthetic Route of 612-13-5.
Referemce:
https://en.wikipedia.org/wiki/Nitrile,
Nitriles – Chemistry LibreTexts