Leal, Raul A. published the artcileApplication of a Palladium-Catalyzed C-H Functionalization/Indolization Method to Syntheses of cis-Trikentrin A and Herbindole B, Application In Synthesis of 68569-14-2, the publication is Angewandte Chemie, International Edition (2016), 55(39), 11824-11828, database is CAplus and MEDLINE.
We describe herein formal syntheses of the indole alkaloids cis-trikentrin A, I, and herbindole B, II, from a common meso-hydroquinone intermediate prepared by a ruthenium-catalyzed [2+2+1+1]-cycloaddition that has not been used previously in natural product synthesis. Key steps include a sterically demanding Buchwald-Hartwig amination as well as a unique C(sp3)-H amination/indole formation. Studies toward a selective desymmetrization of the meso-hydroquinone are also reported.
Angewandte Chemie, International Edition published new progress about 68569-14-2. 68569-14-2 belongs to nitriles-buliding-blocks, auxiliary class Palladium, name is Tetrakis(acetonitrile)palladium(II) Ditriflate, and the molecular formula is C10H12F6N4O6PdS2, Application In Synthesis of 68569-14-2.
Referemce:
https://en.wikipedia.org/wiki/Nitrile,
Nitriles – Chemistry LibreTexts