Andersson, Carlaxel published the artcileThe influence of metal coordination on ligand geometry: the structures of 2-(diphenylphosphino)benzyl methyl ether and bis(2-(diphenylphosphino)benzyl methyl ether)palladium(II)triflate, Recommanded Product: Tetrakis(acetonitrile)palladium(II) Ditriflate, the publication is Journal of Molecular Structure (1999), 479(1), 1-11, database is CAplus.
The structures of 2-(diphenylphosphino)benzyl Me ether (I) and bis(2-(diphenylphosphino)benzyl Me ether)palladium(II)triflate (II) were determined by x-ray crystallog. II is a potential catalyst in organic synthesis and was prepared by treating tetrakis(acetonitrile)palladium bistriflate with 2-(diphenylphosphino)benzyl Me ether in toluene for 16 h at room temperature I crystallizes in monoclinic space group P21/a with a 7.873(2), b 14.805(3), c 14.262(5) Å, β 91.34(3)°, and Z = 4. II crystallizes in triclinic space group P1̅ with a 10.2886(6), b 13.951(1), c 15.6339(9) Å, α 89.171(5), β 73.791(5), γ 83.463(6)°, and Z = 2. Both structures were solved by direct methods and the refinements resulted in the R-values 0.066 and 0.052 for I and II, resp. The bidentate ligand binds to Pd(II) in a cis-configuration. The Pd-O distances are 2.153(3) and 2.142(3) A and the Pd-P distances 2.252(1) and 2.256(1) Å. The effects of packing and metal complexation on the geometry of I are discussed and the differences are compared by half-normal probability plot anal.
Journal of Molecular Structure published new progress about 68569-14-2. 68569-14-2 belongs to nitriles-buliding-blocks, auxiliary class Palladium, name is Tetrakis(acetonitrile)palladium(II) Ditriflate, and the molecular formula is C10H12F6N4O6PdS2, Recommanded Product: Tetrakis(acetonitrile)palladium(II) Ditriflate.
Referemce:
https://en.wikipedia.org/wiki/Nitrile,
Nitriles – Chemistry LibreTexts