Jie, Zhou’s team published research in Journal of Organic Chemistry in 2002-02-08 | CAS: 5653-62-3

Journal of Organic Chemistry published new progress about diethyl chlorophosphite reaction oxygenated functional group. 5653-62-3 belongs to class nitriles-buliding-blocks, name is 2,3-Dimethoxybenzonitrile, and the molecular formula is C9H9NO2, Recommanded Product: 2,3-Dimethoxybenzonitrile.

Jie, Zhou published the artcileDiethyl Chlorophosphite: A Versatile Reagent, Recommanded Product: 2,3-Dimethoxybenzonitrile, the main research area is diethyl chlorophosphite reaction oxygenated functional group.

Di-Et chlorophosphite (DECP) was previously described as a reducing agent for nitro compounds to amines (B. Fischer and L. Sheihet, J. Organic Chem. 1998, 63, 393). Here, the utility of this reagent was extended to chem. conversions of other oxygenated functional groups. In this paper we report on the scope of the reaction of DECP with N-oxides, epoxides, sulfones, sulfoxides, hydroxylamines, ketoximes, and aldoximes. The chemoselectivity of DECP is described, and conditions for a stepwise multiple conversion of functional groups on the same mol. with this reagent are provided.

Journal of Organic Chemistry published new progress about diethyl chlorophosphite reaction oxygenated functional group. 5653-62-3 belongs to class nitriles-buliding-blocks, name is 2,3-Dimethoxybenzonitrile, and the molecular formula is C9H9NO2, Recommanded Product: 2,3-Dimethoxybenzonitrile.

Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts