Kajiwara, Rikuo published the artcileBipyridine-Type Bidentate Auxiliary-Enabled Copper-Mediated C-H/C-H Biaryl Coupling of Phenols and 1,3-Azoles, Quality Control of 87150-13-8, the main research area is heterobiaryl preparation; phenol azole coupling bipyridine type bidentate auxiliary copper.
A copper-mediated dehydrogenative C-H/C-H biaryl coupling of phenols and 1,3-azoles has been developed. The key to its success is the introduction of a bipyridine-type bidentate auxiliary, 4,4′-di(tert-butyl)-2,2′-bipyridine, on the phenol oxygen, which is readily prepared and easily attachable, detachable, and recyclable. The reaction proceeds smoothly in the presence of copper salt alone to form the corresponding phenol-azole heterobiaryls, which are prevalent motifs in functional mols. such as excited-state intramol. proton transfer materials.
Organic Letters published new progress about Coupling reaction. 87150-13-8 belongs to class nitriles-buliding-blocks, name is 4-(5-Oxazolyl)benzonitrile, and the molecular formula is C10H6N2O, Quality Control of 87150-13-8.
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts