Electrochemical oxidation of organic compounds in fluorosulfuric acid. X. Effect of the increase in acidity on the anodic behavior of some aromatic compounds in the fluorosulfuric acid-antimony pentafluoride system was written by Rudenko, A. P.;Zarubin, M. Ya.;Averyanov, S. F.. And the article was included in Journal fuer Praktische Chemie (Leipzig) in 1985.HPLC of Formula: 16144-65-3 The following contents are mentioned in the article:
The electrochem. oxidation of 37 aromatic compounds (nitriles, nitro compounds, amines, sulfonyl fluorides, carbonyl compounds, hydrocarbons, benzylic acetates, MeO compounds) was examined by cyclic voltammetry in HSO3F and 15:1 and 3:1 HSO3F-SbF5 at -76° and, in some cases, in 1:1 HSO3F-SbF5 at -40°. In most cases the half-peak potential underwent a pos. shift as the content of SbF5 was increased. The anodic behavior also depended on the deprotonation rate of the substrate. This study involved multiple reactions and reactants, such as 2,2′,2”-(2,4,6-Trimethylbenzene-1,3,5-triyl)triacetonitrile (cas: 16144-65-3HPLC of Formula: 16144-65-3).
2,2′,2”-(2,4,6-Trimethylbenzene-1,3,5-triyl)triacetonitrile (cas: 16144-65-3) belongs to nitriles. Nitrile carbon shifts are in the range of 115–125 ppm whereas in isonitriles the shifts are around 155–165 ppm. Some nitriles are manufactured by heating carboxylic acids with ammonia in the presence of catalysts. This process is used to make nitriles from natural fats and oils, the products being used as softening agents in synthetic rubbers, plastics, and textiles and for making amines.HPLC of Formula: 16144-65-3
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts