Selective recognition of NH4+ over K+ with tripodal oxazoline receptors was written by Ahn, Kyo Han;Kim, Sung-Gon;Jung, Junyang;Kim, Kyung-Hyun;Kim, Jaheon;Chin, Jik;Kim, Kimoon. And the article was included in Chemistry Letters in 2000.Application In Synthesis of 2,2′,2”-(2,4,6-Trimethylbenzene-1,3,5-triyl)triacetonitrile The following contents are mentioned in the article:
Benzene-based tripodal tris(oxazolines) are found to be promising receptors for the selective recognition of NH4+ over K+ with high binding affinities. This study involved multiple reactions and reactants, such as 2,2′,2”-(2,4,6-Trimethylbenzene-1,3,5-triyl)triacetonitrile (cas: 16144-65-3Application In Synthesis of 2,2′,2”-(2,4,6-Trimethylbenzene-1,3,5-triyl)triacetonitrile).
2,2′,2”-(2,4,6-Trimethylbenzene-1,3,5-triyl)triacetonitrile (cas: 16144-65-3) belongs to nitriles. There has been no report on the microbial biosynthesis of nitriles and the physiological function of such enzymes, nor was it not even known whether aliphatic and aromatic nitriles are biological compounds or just petrochemicals. In conventional organic reductions, nitrile is reduced by treatment with lithium aluminium hydride to the amine. Reduction to the imine followed by hydrolysis to the aldehyde takes place in the Stephen aldehyde synthesis, which uses stannous chloride in acid.Application In Synthesis of 2,2′,2”-(2,4,6-Trimethylbenzene-1,3,5-triyl)triacetonitrile
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts