Mahmoudi, Boshra published the artcileOxidation/ MCR domino protocol for direct transformation of methyl benzene, alcohol, and nitro compounds to the corresponding tetrazole using a three-functional redox catalytic system bearing TEMPO/Co(III)-porphyrin/ Ni(II) complex, Product Details of C6H4N2, the main research area is alc methylbenzene nitro compound conversion tetrazole oxidation multicomponent domino; safety sodium azide.
A redox catalytic system for oxidation-reduction reactions and the domino preparation of tetrazole compounds from nitro and alc. precursors was designed, prepared and characterized by UV-vis, GPC, TGA, XRD, EDX, XPS, VSM, FE-SEM, TEM, DLS, BET, NMR, and ICP analyses [e.g., toluene → 5-phenyl-1H-tetrazole and nitrobenzene → 1-phenyl-1H-tetrazole]. The catalyst was prepared via several successive steps by demetalation of chlorophyll b, Schiff base formation with allylamine, copolymerization with acrylated TEMPO monomers, complexation with Ni and Co metals (in two different steps), then immobilized on magnetic nanoparticles. The presence of three functional groups including TEMPO, coordinated cobalt, and coordinated nickel in the catalyst, allowed the oxidation of various types of alcs., alkyl benzenes as well as the reduction of nitro compounds by a single catalyst. All reactions yielded up to 97% selectivity for oxidation and reduction reactions. Next, the ability of the catalyst to successfully convert benzylic alcs., methylbenzenes and nitro compounds to their corresponding tetrazoles was studied. Safety: extreme caution is required when handling sodium azide.
Molecular Catalysis published new progress about Alkylbenzenes Role: RCT (Reactant), RACT (Reactant or Reagent). 100-70-9 belongs to class nitriles-buliding-blocks, name is Picolinonitrile, and the molecular formula is C6H4N2, Product Details of C6H4N2.
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts