Lian, Zhong published the artcileCooperative redox activation for carbon dioxide conversion, Application In Synthesis of 42872-30-0, the main research area is diaryldisilane carbon dioxide aryl iodide palladium Hiyama Denmark coupling; diarylketone preparation.
The conversion of CO2 with diaryldisilanes, which through cooperative redox activation generated carbon monoxide and a diaryldisiloxane that actively participated in a palladium-catalyzed carbonylative Hiyama-Denmark coupling for the synthesis of an array of pharmaceutically relevant diarylketones was reported. Thus the disilane reagent not only served as the oxygen abstracting agent from CO2, but the silicon-containing ‘waste’, produced through oxygen insertion into the Si-Si bond, participated as a reagent for the transmetalation step in the carbonylative coupling. Hence this concept of cooperative redox activation opened up for new avenues in the conversion of CO2.
Nature Communications published new progress about Aryl ketones Role: SPN (Synthetic Preparation), PREP (Preparation). 42872-30-0 belongs to class nitriles-buliding-blocks, name is 2-(3-Benzoylphenyl)propanenitrile, and the molecular formula is C16H13NO, Application In Synthesis of 42872-30-0.
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts