Hao, Xiaowei published the artcileAir-stable and highly efficient indenyl-derived phosphine ligand: Application to Buchwald-Hartwig amination reactions, Product Details of C11H12N2O, the main research area is palladium complex mesitylindenyldicyclohexylphosphine preparation catalyst Buchwald Hartwig amination; aryl halide Buchwald Hartwig amination palladium catalyst.
2-Mesitylindenyl phosphine ligand (I) and [(2-mesitylindenyl)dicyclohexylphosphine]PdCl2 (II) have been synthesized and fully characterized by NMR and elemental anal., as well as by X-ray crystallog. for II. A Highly active catalyst system derived from a palladium precatalyst and bulky 2-mesitylindenyl phosphine ligand (I) for the Buchwald-Hartwig amination reaction of aryl halides with primary and secondary amines has been developed. This method allows for the preparation of a wide variety of amines in moderate to excellent yields and displays a high level of activity for the coupling of aryl chlorides as well as hindered aryl bromides.
Journal of Organometallic Chemistry published new progress about Aryl bromides Role: RCT (Reactant), RACT (Reactant or Reagent). 204078-32-0 belongs to class nitriles-buliding-blocks, name is 2-Morpholinobenzonitrile, and the molecular formula is C11H12N2O, Product Details of C11H12N2O.
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts