Xiao, Yan published the artcileRhodium-Catalyzed Reaction of Azobenzenes and Nitrosoarenes toward Phenazines, SDS of cas: 1885-29-6, the main research area is azobenzene nitrosoarene rhodium annulation catalyst; phenazine preparation.
A rhodium-catalyzed annulative reaction between azobenzenes and nitrosoarenes has been developed, leading to a series of phenazines I (R1 = H, 2-Cl, 2-MeO, 2-Me, etc.; R2 = H, 2-Me, 2-t-Bu, 2-Br, etc.) in moderate to good yields. This procedure proceeds with sequential chelation-assisted addition of aryl C-H to nitrosoarenes and ring closure by electrophilic attack of azo group to aryl. During this transformation, the azo group served as not only a traceless directing group but also a building block in the final products.
Organic Letters published new progress about Aromatic compounds, nitroso Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 1885-29-6 belongs to class nitriles-buliding-blocks, name is 2-Aminobenzonitrile(Flakes or Chunks), and the molecular formula is C7H6N2, SDS of cas: 1885-29-6.
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts