Moghaddam, Firouz Matloubi published the artcileA ligand and Palladium-free Avenue for Cyanation of Aryl Halides: The Art of Samarium Powder in C-C Coupling Reaction, Computed Properties of 100-70-9, the main research area is benzonitrile preparation green chem chemoselective; aryl halide sodium cyanide cyanation samarium powder catalyst.
This was the first study of samarium powder catalyzed cyanation reaction of aryl halides, bearing electron-withdrawing and electron-releasing substituents, in the presence of NaCN to afford corresponding benzonitriles ArCN [Ar = C6H5, 4-O2NC6H4, naphth-1-yl, etc.] in high yields. This protocol took the advantage of being done in the absence of additive, ligand and precious transition metals such as palladium.
ChemistrySelect published new progress about Aryl halides Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 100-70-9 belongs to class nitriles-buliding-blocks, name is Picolinonitrile, and the molecular formula is C6H4N2, Computed Properties of 100-70-9.
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts