Karges, Johannes published the artcileSynthesis of tetranuclear rhenium(I) tricarbonyl metallacycles, Recommanded Product: Picolinonitrile, the main research area is tetranuclear rhenium tricarbonyl metallacycle preparation structure conformation; crystal structure mol tetranuclear rhenium tricarbonyl metallacycle preparation.
Re(I) tricarbonyl complexes have received much attention due to their attractive photochem., electrochem., and biol. properties. Beyond simple mononuclear complexes, multinuclear assemblies offer greater structural diversity and properties. Despite previous reports on the preparation of di-, tri-, or tetranuclear Re(I) tricarbonyl assemblies, the synthesis of these supramol. structures remains challenging due to overall low yields or tedious purification protocols. Herein, the facile preparation and characterization of tetranuclear Re(I) tricarbonyl metallacycles with a square geometry is reported using a tetrazole-based ligand. The synthesis of the metallacycle was optimized using different metal precursors, solvents, temperatures, and reagent concentrations Finally, the scope of suitable tetrazole-based ligands was explored to produce several tetranuclear Re(I) tricarbonyl-based metallacycles.
Dalton Transactions published new progress about Conformation. 100-70-9 belongs to class nitriles-buliding-blocks, name is Picolinonitrile, and the molecular formula is C6H4N2, Recommanded Product: Picolinonitrile.
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts