On July 19, 2013, Cao, Ying; Zhang, Song-Chen; Zhang, Min; Shen, Guang-Bin; Zhu, Xiao-Qing published an article.Product Details of 2510-01-2 The title of the article was Determination of Thermodynamic Affinities of Various Polar Olefins as Hydride, Hydrogen Atom, and Electron Acceptors in Acetonitrile. And the article contained the following:
A series of 69 polar olefins with various typical structures (X) were synthesized and the thermodn. affinities (defined in terms of the molar enthalpy changes or the standard redox potentials in this work) of the polar olefins obtaining hydride anions, hydrogen atoms, and electrons, the thermodn. affinities of the radical anions of the polar olefins (X•-) obtaining protons and hydrogen atoms, and the thermodn. affinities of the hydrogen adducts of the polar olefins (XH•) obtaining electrons in acetonitrile were determined using titration calorimetry and electrochem. methods. The pure C=C π-bond heterolytic and homolytic dissociation energies of the polar olefins (X) in acetonitrile and the pure C=C π-bond homolytic dissociation energies of the radical anions of the polar olefins (X•-) in acetonitrile were estimated The remote substituent effects on the six thermodn. affinities of the polar olefins and their related reaction intermediates were examined using the Hammett linear free-energy relationships; the results show that the Hammett linear free-energy relationships all hold in the six chem. and electrochem. processes. The information disclosed in this work could not only supply a gap of the chem. thermodn. of olefins as one class of very important organic unsaturated compounds but also strongly promote the fast development of the chem. and applications of olefins. The experimental process involved the reaction of 2-(2,3-Dihydro-1H-inden-1-ylidene)malononitrile(cas: 2510-01-2).Product Details of 2510-01-2
The Article related to thermodn affinity polar olefin hydride hydrogen atom electron acceptor, Physical Organic Chemistry: Other Reactions, Processes, and Spectra and other aspects.Product Details of 2510-01-2
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts