Nitrile is any organic compound with a −C≡N functional group. 1835-49-0, formula is C8F4N2, Name is Tetrafluoroterephthalonitrile.The prefix cyano- is used interchangeably with the term nitrile in literature. Application In Synthesis of 1835-49-0.
Li, Meng;Wu, Mingwei;Pan, Biwei;Xu, Dandan;Lvsong, Zhuopu;Li, Dongqing;Zhang, Fangrong;Huang, Jun research published 《 Aerobic Oxidation of 2,3,6-Trimethylphenol with Reusable Homogenized Copper Catalysts》, the research content is summarized as follows. The oxidation of 2,3,6-trimethylphenol(TMP) can produce both 2,3,5-trimethyl-1,4-benzoquinone(TMQ) and 2,3,5-trimethyl-1,4-hydroquinone(TMHQ) as important intermediates of vitamin E. With a soluble and porous polymer of intrinsic microporosity(PIM-1), we developed a highly active and reusable CuO@PIM-1 catalyst for the aerobic oxidation of TMP to TMQ and TMHQ. The CuO@PIM-1 catalyst is high active and selective for the aerobic oxidation of TMP, and TMQ and TMHQ can be obtained in yields of 81% and 19%, resp. The CuO@PIM-1 catalyst has both advantages of homogeneous and heterogeneous and the CuO@PIM-1 catalyst showed a higher activity than homogeneous(CuCl2) and heterogeneous(supported CuO) catalysts. Moreover, CuO@PIM-1 catalyst can be recovered easily and reused at least 5 times without deactivation.
1835-49-0, Tetrafluoroterephthalonitrile can react with alkyl grignard reagents to form 4-alkyltetraflurorobenzonitriles. It acts as a four electron donor ligand. Tetrafluoroterephthalonitrile can be used to synthesize polymers of intrinsic microporosity. It has been used to study UV rearranged polymers of teh PIM-1 type membrane for the efficient separation of H2 and CO2.
Tetrafluoroterephthalonitrile reacts with alkyl Grignard reagents to form corresponding 4-alkyltetrafluorobenzonitriles. Tetrafluoroterephthalonitrile acts as a four-electron donor ligand and forms tungsten(II)η 2-nitrile complexes.
Tetrafluoroterephthalonitrile is a hydroxyl group-containing organic chemical compound . It has been used in analytical chemistry as a reagent for the determination of peptide binding constants and disulfide bonds. Tetrafluoroterephthalonitrile binds to nucleophilic sites on proteins, such as the pim-1 protein, and can be used to transport other molecules across cell membranes. In addition, it has been used to produce polymers for use in analytical chemistry. This chemical is also able to bind with magnetic particles under constant pressure conditions, which makes it useful for optical sensor applications. , Application In Synthesis of 1835-49-0
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts