《Electrochemical Synthesis of β-Ketonitriles from Aryl Methyl Ketones》 was written by Yavari, Issa; Shaabanzadeh, Sina; Sheikhi, Sara. Recommanded Product: 614-16-4 And the article was included in ChemistrySelect in 2020. The article conveys some information:
A synthesis of β-ketonitriles ArC(O)CH2CN (Ar = Ph, 4-chlorophenyl, naphthalen-2-yl, etc.) by cyanation of aryl Me ketones ArC(O)CH3 with two completely distinct sources of cyanide, namely Me3SiCN and KCN, under metal- and oxidant-free electrochem. anodic oxidation conditions is described. In this approach, a range of β-ketonitriles can be obtained in good yields. This conversion is facilitated by I2, generated in situ from electrochem. oxidation of iodide ion to afford the β-ketonitriles. This environmentally benign method is more convenient and practical compared to previous approaches. In the part of experimental materials, we found many familiar compounds, such as 3-Oxo-3-phenylpropanenitrile(cas: 614-16-4Recommanded Product: 614-16-4)
3-Oxo-3-phenylpropanenitrile(cas: 614-16-4) has been used in the synthesis of substituted naphtho[1,8-bc]pyrans. It was also used as building block in the preparation of 4H-pyrans, 2-pyridones, furans and carbocyclics.Recommanded Product: 614-16-4
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts