Related Products of 1403850-00-9On May 1, 2020 ,《Additions of Aldehyde-Derived Radicals and Nucleophilic N-Alkylindoles to Styrenes by Photoredox Catalysis》 appeared in Organic Letters. The author of the article were Lux, Marcel; Klussmann, Martin. The article conveys some information:
The consecutive addition of acyl radicals and N-alkylindole nucleophiles to styrenes was established, as well as some addnl. radical-nucleophile combinations. Both aryl and aliphatic aldehydes give reasonable yields. The reaction proceeds best for α-substituted styrenes, effectively creating a quaternary all-carbon center. Some iridium-based photoredox systems are catalytically active; furthermore, a base is needed in this transformation. Radicals are formed by reductive perester cleavage and hydrogen atom transfer. In addition to this study using 2,4,6-Tris(diphenylamino)-3,5-difluorobenzonitrile, there are many other studies that have used 2,4,6-Tris(diphenylamino)-3,5-difluorobenzonitrile(cas: 1403850-00-9Related Products of 1403850-00-9) was used in this study.
2,4,6-Tris(diphenylamino)-3,5-difluorobenzonitrile(cas: 1403850-00-9) is cyanoarene-based donor-acceptor photocatalyst developed by the Zeitler group. While this catalyst has a balanced redox profile, allowing for its use in a variety of transformations, it stands out as the most reducing catalyst of the family.Related Products of 1403850-00-9
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts